149706-72-9

Upstream product

• 149706-67-2 (+)-(3R,4R)-3-<<(tert-Butyldiphenylsilyl)oxy>methyl>-4-<(benzyloxy)methyl>hexane-1,6-dicarboxylic acid 
• 149706-66-1 (3R,4R)-3-Benzyloxymethyl-4-(tert-butyl-diphenyl-silanyloxymethyl)-hexanedial 
• 149706-68-3 (-)-(3R,4R)-3-<(Benzyloxy)methyl>-4-<<(tert-butyldiphenylsilyl)oxy>methyl>cyclopentan-1-one 
• 149706-64-9 (-)-(1R,2R)-1-<(Benzyloxy)methyl>-2-<<(tert-butyldiphenylsilyl)oxy>methyl>cyclohex-4-ene 
• 149818-37-1 (-)-(3R,4R)-3-(Hydroxymethyl)-4-<(benzyloxy)methyl>cyclopentan-1-one 
• 149706-69-4 (+)-(1R,3R,4R)-1-Hydroxy-3-(hydroxymethyl)-4-<(benzyloxy)methyl>cyclopentane 
• 149818-36-0 (-)-(1R,2R)-1-(Hydroxymethyl)-2-<(benzyloxy)methyl>cyclohex-4-ene 
• 100-52-7 benzaldehyde 
• 149706-71-8 (+)-(1R,3R,4R)-1-<(2-Methoxyethoxy)methoxy>-3-(hydroxymethyl)-4-<(benzyloxy)methyl>cyclopentane 

Downstream Products

• 149706-73-0 (-)-(1R,2R,4S)-2-<(Benzyloxy)methyl>-4-<(2-methoxyethoxy)methoxy>-1-cyclopentanecarboxylic acid 
• 149706-78-5 (+)-(2S,1'R,2'R,4'S)-1-<2'-<(Benzyloxy)methyl>-4'-<(2-methoxyethoxy)methoxy>-1'-cyclopentyl>-2-hydroxyethanol 
• 149706-74-1 Methyl (-)-(1R,2R,4S)-2-<(Benzyloxy)methyl>-4-<(2-methoxyethoxy)methoxy>-1-cyclopentanecarboxylate 
• 149706-79-6 (-)-(4S,1'R,2'R,4'S)-2,2-Dimethyl-4-<2'-<(benzyloxy)methyl>-4'-<(2-methoxyethoxy)methoxy>-1'-cyclopentyl>-1,3-dioxolane 
• 149706-75-2 (+)-<1'R,2'R,4'S,(S)R>-1-<2'-<(Benzyloxy)methyl>-4'-<(2-methoxyethoxy)methoxy>-1'-cyclopentyl>-2-(p-tolylsulfinyl)ethanone 

Relevant academic research and scientific papers

Enantioselective Synthesis of (+)-Brefeldin A

A new enantioselective synthesis of (+)-brefeldin A is described.The five chiral centers are created by the following methodology: asymmetric Diels-Alder reaction to prepare the cyclopentanone 13, stereocontrolled reduction of the carbonyl in the ketone 14, stereocontrolled creation of the chiral centers C-4 and C-15 by a chiral sulfoxide group.