149793-72-6

Upstream product

• 7225-53-8 (-)-1,6-anhydro-4-O-benzoyl-β-D-mannopyranose 
• 824-94-2 p-methoxybenzyl chloride 
• 131940-20-0 (-)-1,6-anhydro-4-O-benzoyl-2,3-isopropylidene-β-D-mannopyranose 
• 14440-51-8 1,6-anhydro-2,3-O-isopropylidene-β-D-mannopyranose 
• 98-88-4 benzoyl chloride 

Downstream Products

• 144152-57-8 2'-methyl-(3-C-acetyl-1,6-anhydro-3-deoxy-2-O-(p-methoxybenzyl)-β-D-altropyranosido)-<3,4:4',5'>-Δ^2'-oxazoline 
• 144152-56-7 2'-methyl-(1,6-anhydro-3-deoxy-3-C-formyl-2-O-(p-methoxybenzyl)-β-D-altropyranosido)-<3,4:4',5'>-Δ^2'-oxazoline 
• 144152-54-5 (1R,2S,6R,7S,8R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-1-iodo-ethyl]-7-(4-methoxy-benzyloxy)-4-trichloromethyl-3,9,11-trioxa-5-aza-tricyclo[6.2.1.0^2,6]undec-4-ene 
• 144152-55-6 2'-methyl-(1,6-anhydro-3-deoxy-2-O-(p-methoxybenzyl)-3-C-vinyl-β-D-altropyranosido)-<3,4:4',5'>-Δ^2'-oxazoline 
• 144152-51-2 1,6-anhydro-4-O-benzoyl-2-O-(p-methoxybenzyl)-β-D-arabino-hexopyran-3-ulose 

Relevant academic research and scientific papers

Carbohydrates to carbocycles: Synthesis of the densely functionalized carbocyclic core of tetrodotoxin by radical cyclization of an anhydro sugar precursor

The core of tetrodotoxin is a densely functionalized carbocycle for which an annulated pyranose can be envisaged as a retron. The carbocyclic ring is constructed upon a rigid 1,6-anhydro template which permits the early introduction of the key angular nit