149879-69-6Relevant articles and documents
Synthesis of cored dendrimers with internal cross-links
Schultz, Laura G.,Zhao, Yan,Zimmerman, Steven C.
, p. 1962 - 1966 (2001)
Hydrolytic removal of the core unit and cross-linking of their wedges enables dendrimers to be "cored" (see schematic representation). By internalizing the alkenes, the ring-closing metathesis reaction will "stitch" the dendritic wedges to gather intramolecularly, even at dendrimer concentrations of 10-3M. In contrast peripheral alkenes react intermolecularly at this concentration.