1499-29-2Relevant academic research and scientific papers
Rh(III)-catalyzed, 1,2,3-triazole-assisted directed C–H coupling with diazo diphosphonates
Yu, Zhu-Jun,Zhang, Chen,Li, Jiang-Lian,Liu, Yan-Zhao,Yu, Xin-Ling,Guo, Li,Li, Guo-Bo,Wu, Yong
supporting information, p. 2816 - 2819 (2018/06/19)
A mild and efficient procedure was developed for the [Cp?Rh(III)]-catalyzed, 1,2,3-triazole directed C–H coupling with diazomethylene-diphosphonates. This protocol provided a step- and atom-economical protocol for C–C bond formation and led to structurally diverse 2-(1,2,3-triazol-2-yl)benzyl diphosphonates in good to excellent yields.
Preparation of organohalosilanes
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, (2008/06/13)
In an industrial process for preparing organohalosilanes by reacting metallic silicon particles with an organohalide in the presence of a copper catalyst, a contact mass composed of the metallic silicon and the catalyst further contains an effective amount of a phosphine chalcogenide compound. The invention drastically increases the silane formation rate and the utilization of silicon without lowering the selectivity of useful silane.
Synthesis and Nuclear Magnetic Resonance Spectroscopic Studies of Alkylene / Alkylidenebis(phosphonic Dihalides) and -bis(fluorophosphoranes)
Althoff, Wolfgang,Fild, Manfred,Schmutzler, Reinhard
, p. 1082 - 1090 (2007/10/02)
Chlorine-fluorine exchange in the bis(phosphonic dichlorides) Cl2P(O)-X-P(O)Cl2 (1a - c) with AsF3 furnishes the bis(phosphonic difluorides) F2P(O)-X-P(O)F2 (2a - c).Reaction of 2a - c with SF4 leads to bis(tetrafluorophosphoranes) F4P-X-PF4 (3a - c) (X = CH2, CH2CH2, trans-CH=CH).Additional methods of synthesis are indicated for compound 3a (X = CH2) which are based on the cleavage of the Si-C bond with PF5 in the Si-C bonded precursors 2 and Me3SiCH2PF4.The NMR spectra of compounds 2 and 3 are discussed.
