149922-98-5Relevant academic research and scientific papers
Hydroxoiridium/Chiral Diene Complexes as Effective Catalysts for Asymmetric Annulation of α-Oxo- and Iminocarboxamides with 1,3-Dienes
Hatano, Miyuki,Nishimura, Takahiro
supporting information, p. 10949 - 10952 (2015/09/15)
The asymmetric [3+2] annulation of α-oxo- and α-iminocarboxamides with 1,3-dienes catalyzed by hydroxoiridium/chiral diene complexes was realized, giving high yields of the corresponding γ-lactams with high enantioselectivity. [3+2] annulation: The asymme
Organocatalytic asymmetric synthesis of functionalized 1,3,5- triarylpyrrolidin-2-ones via an aza-Michael/aldol domino reaction
Joie, Celine,Deckers, Kristina,Enders, Dieter
, p. 799 - 808 (2014/04/03)
The organocatalytic asymmetric synthesis of functionalized 1,3,5-triarylpyrrolidin-2-ones bearing three contiguous stereocenters through an aza-Michael/aldol domino reaction of α-ketoamides with α,β-unsaturated aldehydes is described. The domino products
Enantio- and chemoselective Br?nsted-acid/Mg(nBu) 2 catalysed reduction of α-keto esters with catecholborane
Enders, Dieter,St?ckel, Bianca A.,Rembiak, Andreas
supporting information, p. 4489 - 4491 (2014/04/17)
The first enantio- and chemoselective Br?nsted-acid catalysed reduction of α-keto esters with catecholborane has been developed. The α-hydroxy esters were obtained under mild reaction conditions in virtually quantitative yields and excellent enantioselectivities. With slight modifications both enantiomers can be obtained without any loss of selectivity. This journal is the Partner Organisations 2014.
Copper-catalyzed B-H bond insertion reaction: A highly efficient and enantioselective C-B bond-forming reaction with amine-borane and phosphine-borane adducts
Cheng, Qing-Qing,Zhu, Shou-Fei,Zhang, Yong-Zhen,Xie, Xiu-Lan,Zhou, Qi-Lin
supporting information, p. 14094 - 14097 (2013/10/21)
A copper-catalyzed B-H bond insertion reaction with amine- and phosphine-borane adducts was realized with high yield and enantioselectivity under mild reaction conditions. The B-H bond insertion reaction provides a new C-B bond-forming methodology and an
The preparation of 2H-1,4-benzoxazin-3-(4H)-ones via palladium-catalyzed intramolecular C-O bond formation
Ylijoki, Kai E. O.,Kuendig, E. Peter
supporting information; experimental part, p. 10608 - 10610 (2011/11/05)
Pd/PtBu3-catalyzed intramolecular C-O bond formation has been used to access aryl- and alkyl-substituted benzoxazinones.
Process of producing intermediates for use in production of alkoxyiminoacetamides and intermediates to be used therein
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, (2008/06/13)
There is disclosed a process of producing an α-ketamide as an intermediate for use in the production of various alkoxyiminoacetamide compounds which are useful as fungicides. Also disclosed is an intermediate to be used in this process.
