149935-34-2Relevant academic research and scientific papers
Chemically Fueled Transient Geometry Changes in Diphenic Acids
Hartley, C. Scott,Jayalath, Isuru M.,Kariyawasam, Lasith S.,Mantel, Georgia,Wang, Hehe
, p. 7567 - 7571 (2020)
Transient changes in molecular geometry are key to the function of many important biochemical systems. Here, we show that diphenic acids undergo out-of-equilibrium changes in dihedral angle when reacted with a carbodiimide chemical fuel. Treatment of appropriately functionalized diphenic acids with EDC (N-(3-(dimethylamino)propyl)-N′-ethylcarbodiimide hydrochloride) yields the corresponding diphenic anhydrides, reducing the torsional angle about the biaryl bond by ~45°, regardless of substitution. In the absence of steric resistance, the reaction is well-described by a simple mechanism; the resulting kinetic parameters can be used to derive important properties of the system, such as yields and lifetimes. The reaction tolerates steric hindrance ortho to the biaryl bond, although the competing formation of (transient) byproducts complicates quantitative analysis.
The unusual electrochemical and photophysical behavior of 2,2′-bis(1,3,4-oxadiazol-2-yl)biphenyls, effective electron transport hosts for phosphorescent organic light emitting diodes
Leung, Man-Kit,Yang, Chih-Chiang,Lee, Jiun-Haw,Tsai, Hsin-Hung,Lin, Chi-Feng,Huang, Chih-Yen,Su, Yuhlong Oliver,Chiu, Chi-Feng
, p. 235 - 238 (2007/10/03)
(Chemical Equation Presented) The fluorescence and phosphorescence of 2,2′-bis(5-phenyl-1,3,4-oxadiazol-2-yl)biphenyl shows good spectral matching with the absorption spectra of the MLCT1 and MLCT 3 transitions of Ir(ppy)3
Water-soluble polyimides and methods of making and using same
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Page/Page column 15, (2008/06/13)
The present invention provides, among other things, water-soluble polyimides, methods of making water-soluble polyimides, and methods of using water-soluble polyimides, e.g., in optics applications as well as other applications.
Palladium-catalyzed reactions of bisarenediazoniutn salts: Two-fold Heck reaction, carbonylation and cross-coupling regimen
Sengupta, Saumitra,Sadhukhan, Subir Kumar,Bhattacharyya, Sanchita,Guha, Joydeep
, p. 407 - 410 (2007/10/03)
Two-fold Heck reaction, carbonylation and cross-coupling reactions of bisarenediazonium salts have been carried out in high yields under mild, aqueous alcoholic conditions to provide a new synthetic repertoire for tetraaryls and other aromatic derivatives having extended conjugation.
