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150207-04-8

nickel(II) diphenylglyoxal-bis(S-methylisothiocarbohydrazonate) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 150207-04-8 Structure

  • Basic information

    1. Product Name: nickel(II) diphenylglyoxal-bis(S-methylisothiocarbohydrazonate)
    2. Synonyms: nickel(II) diphenylglyoxal-bis(S-methylisothiocarbohydrazonate)
    3. CAS NO:150207-04-8
    4. Molecular Formula:
    5. Molecular Weight: 471.232
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 150207-04-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: nickel(II) diphenylglyoxal-bis(S-methylisothiocarbohydrazonate)(CAS DataBase Reference)
    10. NIST Chemistry Reference: nickel(II) diphenylglyoxal-bis(S-methylisothiocarbohydrazonate)(150207-04-8)
    11. EPA Substance Registry System: nickel(II) diphenylglyoxal-bis(S-methylisothiocarbohydrazonate)(150207-04-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 150207-04-8(Hazardous Substances Data)

150207-04-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 150207-04-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,0,2,0 and 7 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 150207-04:
(8*1)+(7*5)+(6*0)+(5*2)+(4*0)+(3*7)+(2*0)+(1*4)=78
78 % 10 = 8
So 150207-04-8 is a valid CAS Registry Number.

150207-04-8Relevant articles and documents

Nickel(II) Complexes with Redox Noninnocent Octaazamacrocycles as Catalysts in Oxidation Reactions

Dobrov, Anatolie,Darvasiová, Denisa,Zalibera, Michal,Bu?insky, Luká?,Pu?kárová, Ingrid,Rapta, Peter,Shova, Sergiu,Dumitrescu, Dan,Martins, Luísa M.D.R.S.,Pombeiro, Armando J.L.,Arion, Vladimir B.

, p. 11133 - 11145 (2019/08/20)

Nickel(II) complexes with 15-membered (1-5) and 14-membered (6) octaazamacrocyclic ligands derived from 1,2- and 1,3-diketones and S-methylisothiocarbohydrazide were prepared by template synthesis. The compounds were characterized by elemental analysis, electrospray ionization mass spectrometry, IR, UV-vis, 1H NMR spectroscopies, and X-ray diffraction. The complexes contain a low-spin nickel(II) ion in a square-planar coordination environment. The electrochemical behavior of 1-6 was investigated in detail, and the electronic structure of 1e-oxidized and 1e-reduced species was studied by electron paramagnetic resonance, UV-vis-near-IR spectroelectrochemistry, and density functional theory calculations indicating redox noninnocent behavior of the ligands. Compounds 1-6 were tested in the microwave-assisted solvent-free oxidation of cyclohexane by tert-butyl hydroperoxide to produce the industrially significant mixture of cyclohexanol and cyclohexanone (i.e., A/K oil). The results showed that the catalytic activity was affected by several factors, namely, reaction time and temperature or amount and type of catalyst. The best values for A/K oil yield (23%, turnover number of 1.1 × 102) were obtained with compound 6 after 2 h of microwave irradiation at 100 °C.

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