15024-08-5

Basic information

• Product Name: Benzoic acid, 4-methyl-, 4-methylphenyl ester
• CAS NO: 15024-08-5
• Molecular Formula: C15H14O2
• Molecular Weight: 226.275
• Mol File: 15024-08-5.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-methyl-, 4-methylphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-methyl-, 4-methylphenyl ester(15024-08-5)
• EPA Substance Registry System: Benzoic acid, 4-methyl-, 4-methylphenyl ester(15024-08-5)

Safety Data

• Hazardous Substances Data: 15024-08-5(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 106-44-5 p-cresol 
• 106-43-4 para-chlorotoluene 
• 13222-85-0 p-methylbenzoic anhydride 
• 99-94-5 p-Toluic acid 
• 201230-82-2 carbon monoxide 
• 15088-74-1 4-methylbenzoic dithioperoxyanhydride 
• 874-60-2 4-methyl-benzoyl chloride 
• 104-87-0 4-methyl-benzaldehyde 
• 25563-06-8 N-methoxy-4-methylbenzamide 
• 624-31-7 4-tolyl iodide 
• 106-49-0 p-toluidine 
• 106-42-3 para-xylene 

Downstream Products

• 916988-26-6 4-Methyl-benzoic acid 2-benzoyl-4-methyl-phenyl ester 
• 16762-24-6 2-(4-methylphenyl)-3-phenyl-5-methylbenzofuran 
• 1470-57-1 2-hydroxy-5-methylbenzophenone 
• 99-94-5 p-Toluic acid 
• 116544-65-1 (2-Benzoyl-4-methyl-phenoxy)-p-tolyl-acetic acid 
• 116544-55-9 (2-Benzoyl-4-methyl-phenoxy)-p-tolyl-acetic acid ethyl ester 
• 6947-86-0 6-methyl-3-phenyl-4-p-tolyl-coumarin 
• 126583-40-2 (2-Hydroxy-5-methyl-phenyl)-p-tolyl-methanone oxime 
• 126583-42-4 (2-Hydroxy-5-methyl-phenyl)-p-tolyl-methanone oxime 
• 794513-62-5 4-methyl-benzoic acid 4-methyl-2-(4-methyl-benzoyl)-phenyl ester 
• 106-44-5 p-cresol 
• 937-21-3 4-methylperbenzoic acid 
• 26880-95-5 (4-methylphenyl)(2-hydroxy-5-methylphenyl)methanone 

Relevant articles and documents

Electrodimerization of N-Alkoxyamides for Zinc(II) Catalyzed Phenolic Ester Synthesis under Mild Reaction Conditions

An electrochemical On-Off method for phenolic ester synthesis from N-alkoxyamides has been reported. This one-pot protocol begins with rapid and selective electrodimerization of the amide using n-Bu4NI (TBAI) as an electrocatalyst. The reaction proceeds further in the absence of current via Zn catalyzed C?N bond activation of the amide dimer followed by its coupling with phenol to form the ester. The present methodology is ligand-free and takes place under mild reaction conditions. This transformation incorporates a wide variety of phenols and amide substrates leading to the formation of functionalized esters highlighting its versatility. (Figure presented.).

Diacyl Disulfide: A Reagent for Chemoselective Acylation of Phenols Enabled by 4-(N,N-Dimethylamino)pyridine Catalysis

A general and excellent acylation reagent, diacyl disulfide, was uncovered for efficient ester formation enabled by DMAP (4-(N,N-dimethylamino)pyridine) catalysis. This protocol offered a promising synthetic platform on site-selective acylation of phenolic and primary aliphatic hydroxyl groups, which greatly expanded the realm of protecting group chemistry. The importance of the reagent was also reflected by its excellent moisture tolerance, high efficiency, and potential in synthetic chemistry and biologically meaningful natural product modification.

Significant promoting effects of Lewis acidity on Au-Pd systems in the selective oxidation of aromatic hydrocarbons

An unprecedented synergistic effect, obtained for rationally designed Au-Pd alloy nanoparticles supported on an acidic metal-organic framework (MOF), in the aerobic oxidation of the primary C-H bonds in toluene and derivates is reported.