150367-14-9

Basic information

• Product Name: C₁₆H₁₇NO₂Se
• CAS NO: 150367-14-9
• Molecular Weight: 334.276
• Mol File: 150367-14-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₁₇NO₂Se(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₁₇NO₂Se(150367-14-9)
• EPA Substance Registry System: C₁₆H₁₇NO₂Se(150367-14-9)

Safety Data

• Hazardous Substances Data: 150367-14-9(Hazardous Substances Data)

Upstream product

• 5153-67-3 nitrostyrene 
• 34837-55-3 Phenylselenyl bromide 
• 119880-63-6 [1-(nitromethyl)propyl]benzene 

Downstream Products

• 119880-58-9 (E)-(1-nitrobut-1-en-2-yl)benzene 

Relevant articles and documents

A General Method for the Preparation of 2,2-Disubstituted 1-Nitroalkenes

A general and expeditious route for the preparation of functionalized 2,2-disubstituted 1-nitroalkenes has been developed.Conjugate 1,4-addition of complex zinc cuprates (RCu(CN)ZnI) to easily obtained (E)-1-nitroalkenes, followed by trapping with phenylselenenyl bromide and subsequent oxidative elimination, afforded the corresponding 2,2-disubstituted 1-nitroalkenes in good yields. 2-Alkyl-2-aryl- and 2,2-dialkyl nitroalkenes 4b-g were prepared in 76-88percent yield and obtained as E/Z isomeric mixtures, slightly favoring the Z isomer (ca. 1.0:1.5, E/Z).