150374-55-3Relevant academic research and scientific papers
Intramolecular Alkoxycobaltation: a Novel Route to the Cobalt-Carbon Bond in a Coenzyme B12 Model
Kingma, Irene E.,Wiersma, Marten,Baan, Juul L. van der,Balt, Sijbe,Bickelhaupt, Friedrich,et al.
, p. 832 - 834 (2007/10/02)
Co(II)(salen) derivatives whose ethanediyl moiety carries an ω-alkenyl side chain react with oxygen and methanol or ethanol to give, via interaction between intermediate Co(III) species and the pendant olefin, alkylated products with a β-alkoxy substituted carbon bridge between cobalt and the equatorial ligand; the corresponding intermolecular reaction between Co(II)(salen) and hex-1-ene does not take place.
