150374-52-0Relevant academic research and scientific papers
Intramolecular Alkoxycobaltation: a Novel Route to the Cobalt-Carbon Bond in a Coenzyme B12 Model
Kingma, Irene E.,Wiersma, Marten,Baan, Juul L. van der,Balt, Sijbe,Bickelhaupt, Friedrich,et al.
, p. 832 - 834 (1993)
Co(II)(salen) derivatives whose ethanediyl moiety carries an ω-alkenyl side chain react with oxygen and methanol or ethanol to give, via interaction between intermediate Co(III) species and the pendant olefin, alkylated products with a β-alkoxy substituted carbon bridge between cobalt and the equatorial ligand; the corresponding intermolecular reaction between Co(II)(salen) and hex-1-ene does not take place.
Bridged (β-alkoxyalkyl)CoIII(salen) complexes by intramolecular alkoxycobaltation of unactivated alkenes: New models for coenzyme B12
Blaauw, Rolf,Kingma, Irene E.,Laan, Jan H.,Van Der Baan, Juul L.,Balt, Sijbe,De Bolster, Martinus W. G.,Klumpp, Gerhard W.,Smeets, Wilberth J. J.,Spek, Anthony L.
, p. 1199 - 1210 (2007/10/03)
CoII(salen) derivatives (salen = {N,N′-ethylenebis[salicylideneaminato]}) whose ethanediyl moiety carries an alkenyl side-chain R [R = prop-2-en-1-yl (6a), 2-methylprop-2-en-1-yl (6b), but-2-en-1-yl (6c), but-3-en-1-yl (6d)] react with oxygen a
