15040-95-6Relevant academic research and scientific papers
DoE (Design of Experiments) assisted allylic hydroxylation of enones catalysed by a copper-aluminium mixed oxide
Garcia-Cabeza, Ana Leticia,Marin-Barrios, Ruben,Azarken, Redouan,Moreno-Dorado, F. Javier,Ortega, Maria J.,Vidal, Hilario,Gatica, Jose M.,Massanet, Guillermo M.,Guerra, Francisco M.
, p. 8307 - 8314 (2014/01/06)
The allylic hydroxylation of enones using dioxygen as the oxidant has been studied. The reaction was first examined in the absence of any catalyst, using β-ionone as a model substrate. Then a new copper-aluminium mixed oxide, Cu-Al Ox, was prepared and ch
A Novel Synthesis Including Asymmetric Synthesis of α,β-Unsaturated γ-Hydroxy Carbonyl Compounds from Enones with Carbon Homologation
Satoh, Tsuyoshi,Motohashi, Shigeyasu,Tokutake, Norio,Yamakawa, Koji
, p. 2966 - 2973 (2007/10/02)
Reaction of the carbanion derived from 1-chloroalkyl aryl sulfoxides with enones gave 1,2-adducts in good yields.Treatment of the adduct with potassium benzenethiolate afforded α-phenylthio β,γ-unsaturated carbonyl compound through an α,β-epoxy sulfoxide.
A NOVEL SYNTHESIS OF α,β-UNSATURATED γ-HYDROXY CARBONYL COMPOUNDS FROM ENONES WITH CARBON HOMOLOGATION
Satoh, Tsuyoshi,Motohashi, Shigeyasu,Yamakawa, Koji
, p. 2889 - 2892 (2007/10/02)
The alkylation of enone with 1-chloroalkyl phenyl sulfoxide followed by treatment with thiophenolate afforded α-phenylthio-β,γ-unsaturated carbonyl compound, which was oxidized and then hydrolyzed to give α,β-unsaturated γ-hydroxy carbonyl compound in good yield.
