150456-10-3

Basic information

• Product Name: (2R,3S)-1-benzyl-3-benzyloxy-2-(tert-butyldiphenyl silyloxy)methyl-azetidine
• Synonyms: (2R,3S)-1-benzyl-3-benzyloxy-2-(tert-butyldiphenyl silyloxy)methyl-azetidine
• CAS NO: 150456-10-3
• Molecular Weight: 521.775
• Mol File: 150456-10-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S)-1-benzyl-3-benzyloxy-2-(tert-butyldiphenyl silyloxy)methyl-azetidine(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S)-1-benzyl-3-benzyloxy-2-(tert-butyldiphenyl silyloxy)methyl-azetidine(150456-10-3)
• EPA Substance Registry System: (2R,3S)-1-benzyl-3-benzyloxy-2-(tert-butyldiphenyl silyloxy)methyl-azetidine(150456-10-3)

Safety Data

• Hazardous Substances Data: 150456-10-3(Hazardous Substances Data)

Upstream product

• 150456-08-9 2-O-benzyl-4-O-tert-butyldiphenylsilyl-L-threitol 
• 107938-31-8 (2S,3S)-1,3-O-Benzylidene-2-O-benzylthreitol 
• 84379-51-1 2-O-benzyl-L-threitol 
• 150456-09-0 2-O-benzyl-4-O-tert-butyldiphenylsilyl-1,3-di-O-methylsufonyl-L-threitol 
• 100-46-9 benzylamine 

Downstream Products

• 150456-13-6 (2S,3S)-1-benzyl-3-benzyloxy-2-formyl-azetidine 
• 150456-11-4 (2R,3S)-1-benzyl-3-benzyloxy-2-hydroxymethyl-azetidine 

Relevant articles and documents

Synthesis Of Highly Functionalized Homochiral Azetidines And Azetidine-2-Carboxylic Esters

Homochiral (2S,3S)-3-benzyloxy-2-formyl-azetidines 2, (2S,3S)-3-benzyloxy-2-carbomethoxy-azetidines 3 and the highly strained (2S)-N-p-methoxyphenyl-2-silyloxymethyl-3-azetidinone 4 were successfully synthesized starting from diethyl-L-tartrate.The suitably functionalized azetidine ring is formed in a single synthetic operation with minimum protecting group chemistry.Key Words: Polyhydroxylated azetidines, 2-carbomethoxy-3-hydroxy-azetidines, 2-hydroxymethyl-3-azetidinone