150562-30-4

Basic information

• Product Name: Benzenemethanamine, N-(4-methoxyphenyl)-a-2-propenyl-
• CAS NO: 150562-30-4
• Molecular Formula: C17H19NO
• Molecular Weight: 253.344
• Mol File: 150562-30-4.mol
• Article Data: 40

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-(4-methoxyphenyl)-a-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-(4-methoxyphenyl)-a-2-propenyl-(150562-30-4)
• EPA Substance Registry System: Benzenemethanamine, N-(4-methoxyphenyl)-a-2-propenyl-(150562-30-4)

Safety Data

• Hazardous Substances Data: 150562-30-4(Hazardous Substances Data)

Upstream product

• 783-08-4 [4-(benzylideneamino)phenyl]methanol 
• 106-95-6 allyl bromide 
• 24850-33-7 allyltributylstanane 
• 100-52-7 benzaldehyde 
• 104-94-9 4-methoxy-aniline 
• 1613-90-7 4-methoxy-N-[(E)-phenylmethylidene]aniline 
• 688-61-9 Triallylborane 
• 762-72-1 allyl-trimethyl-silane 
• 1730-25-2 allylmagnesium bromide 
• 116027-51-1 N,N-bis-(4-methoxyphenyl)-1,2-diphenylethane-1,2-diamine 
• 7393-43-3 tetraallyl tin 
• 383-67-5 allyl trifluoroacetate 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 911482-75-2 allylboronic acid 2,2-dimethyl-1,3-propanediol ester 

Downstream Products

• 76403-31-1 (1-Phenyl-but-3-enyl)-carbamic acid methyl ester 
• 4383-23-7 1-phenyl-but-3-enylamine 
• 426825-64-1 (4-methoxy-phenyl)-(1-phenyl-but-3-enyl)-carbamic acid methyl ester 

Relevant articles and documents

Allylic Tantalums as Highly Imine-Selective Reagents

A pratical method for the allylation of low electrophilic N-aliphatic imines was established by allylic tantalum. This is a superior methodology compared with conventional ones in terms of wide applicability to imines.

Organic Photoredox-Catalyzed Synthesis of δ-Fluoromethylated Alcohols and Amines via 1,5-Hydrogen-Transfer Radical Relay

The hydrotrifluoromethylation of benzyl-protected homoallylic alcohol and amine derivatives catalyzed by 2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile (4CzIPN) was developed. This reaction delivered δ-fluoromethylated free alcohols and amines with in situ deprotection of benzyl protecting group under mild irradiation conditions. 4CzIPN was found to be a competent metal-free photoredox catalyst for activating several types of fluoromethylation reagents including CF3SO2Cl, Togni's reagent, and 2-bromo-2,2-difluoroacetate via oxidative quenching and also CF3SO2Na through reductive quenching to allow direct hydrotrifluoromethylation of simple alkenes and Michael acceptors.

Synthesis of homoallylic amines and acylhydrazides by tin powder-promoted multicomponent one-pot allylation reactions

An efficient process for the synthesis of homoallylic amines and N′-homoallylic hydrazides is developed from the one-pot reaction of carbonyl compounds, amines or N-acylhydrazines, allyllic bromide and tin powder using water as solvent. N-Acylhydrazines are found to be more reactive than amines in these processes. They can react not only with aldehydes but also with ketones to give the corresponding N′-homoallylic hydrazides. Copyright

Sn-mediated one-pot four-component allylation of aldimines

A convenient and facile method for the synthesis of homoallylic amines was disclosed. The one-pot reaction of aldehydes, aromatic amines and allylic bromide with tin powder at room temperature could afford the homoallylic amines in good to excellent yield