15070-92-5Relevant articles and documents
Polyfluorinated cyclopentadienones as lewis acids
Inés, Blanca,Holle, Sigrid,Bock, Dominique A.,Alcarazo, Manuel
, p. 1539 - 1541 (2014)
The ability of 2,3,4,5-tetrakis(trifluoromethyl)cyclopenta-2,4-dien-1-one and 2,3,4,5-tetrakis(pentafluorophenyl)cyclopenta-2,4-dien-1-one to act as organic Lewis acids in the field of frustrated Lewis pair (FLP) chemistry was evaluated. Whereas the forme
Synthesis and properties of novel perylenebisimide-cored dendrimers
Ren, Huicai,Li, Jiuyan,Zhang, Ting,Wang, Renjie,Gao, Zhanxian,Liu, Di
experimental part, p. 298 - 303 (2012/07/14)
A group of perylenebisimide-cored dendrimers with polyphenylene dendrons at four bay positions were synthesized and characterized. The electron-deficient pentafluorophenyl or cyano groups were grafted at the dendrimer surface with the aim to further increase the n-type features of the resulted dendrimers. The electrochemical and optical properties were investigated. All the dendrimers show good solubility and film-forming properties, high EA values of 3.8-3.9 eV, and high fluorescent quantum yields. All these merits indicate that they are potential multifunctional materials for application in optoelectronic devices such as solar cells or organic light-emitting devices.
Catalyst system for the polymerization of olefins
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, (2008/06/13)
The present invention relates to a metal-free cyclopentadienide compound which, in conjunction with a metallocene, is able to form a catalyst system that can be used for the polymerization of olefins. It is thus possible to dispense with the use of methylaluminoxane (MAO) or boron-containing compounds as co-catalyst and nevertheless achieve a high degree of catalytic activity. The invention relates also to a process for the preparation of the metal-free cyclopentadienide compound and to the use thereof as a catalyst component in the preparation of polyolefins.