1508308-83-5Relevant academic research and scientific papers
Activation of C-F and Ni-C bonds of [P,S]-ligated nickel perfluorometallacycles
Giffin, Kaitie A.,Harrison, Daniel J.,Korobkov, Ilia,Baker, R. Tom
, p. 7424 - 7430 (2014/04/03)
The first example of a [P,S]-ligated metal perfluorocyclopentane is reported. The new metallacycle undergoes Cα-F activation in the presence of a Lewis acid, followed by chemoselective ligand migration, affording a fused metallabicyclic product. Reactivity of this product includes an unprecedented nucleophile-induced ring-opening reaction, involving loss of a β-fluoride. Additionally, hydrolysis of the metallabicyclic product affords a single isomer of hexafluoro-1-butene.
