150849-75-5Relevant academic research and scientific papers
Iodine Monobromide (IBr) at Low Temperature: Enhanced Diastereoselectivity in Electrophilic Cyclizations of Homoallylic Carbonates
Duan, James J.-W.,Smith, Amos B.
, p. 3703 - 3711 (2007/10/02)
Iodine monobromide affords superior diastereoselectivity in low-temperature electrophilic cyclizations of homoallylic carbonates.Solvent and temperature effects and the scope and limitations of the method are discussed; optimal selectivity is obtained in
Iodine monobromide (IBr) at low temperature: A superior protocol for diastereoselective cyclizations of homoallylic carbonates
Duan, James J. -W.,Sprengeler, Paul A.,Smith III, Amos B.
, p. 6439 - 6442 (2007/10/02)
Iodine monobromide (IBr) induces efficient electrophilic cyclizations of homoallylic t-butyl carbonates in toluene or methylene chloride at low temperature, affording significantly better diastereoselectivity than iodine (I2) in acetonitrile.
