20967-51-5

Upstream product

• 18516-19-3 2,2-dimethyl-3-oxopropyl 4-methylbenzenesulfonate 
• 3111-52-2 potassium thiophenolate 
• 7205-91-6 phenylthiomethyl chloride 
• 6651-34-9 2-methyl-1-(trimethylsilyloxy)-1-propene 
• 51916-36-0 2-Phenylthiomethyl-2-methyl-1-propanol 
• 21651-04-7 3-hydroxy-2,2-dimethylpropyl 4-methylbenzenesulfonate 
• 37972-89-7 2-iodo-benzenethiol 
• 147159-26-0 2,2-Dimethyl-3-phenylsulfanyl-propionic acid methyl ester 

Downstream Products

• 86255-85-8 [2,2-Dimethyl-3-phenylsulfanyl-prop-(Z)-ylideneamino]-acetic acid ethyl ester 
• 150757-36-1 (3S,4S)-4-Methoxymethoxy-2,2-dimethyl-1-phenylsulfanyl-hex-5-en-3-ol 
• 86767-55-7 2-(1,1-Dimethyl-2-phenylsulfanyl-ethyl)-[1,3]dioxolane 
• 86255-87-0 [(2S,3R)-2-(1,1-Dimethyl-2-phenylsulfanyl-ethyl)-3-methoxy-4-oxo-azetidin-1-yl]-acetic acid 
• 86255-86-9 [(2R,3S)-2-(1,1-Dimethyl-2-phenylsulfanyl-ethyl)-3-methoxy-4-oxo-azetidin-1-yl]-acetic acid ethyl ester 
• 86269-27-4 [(2R,3S)-2-(1,1-Dimethyl-2-phenylsulfanyl-ethyl)-3-methoxy-4-oxo-azetidin-1-yl]-acetic acid 2-trimethylsilanyl-ethyl ester 
• 86255-88-1 [(2R,3S)-2-(2-Chloro-1,1-dimethyl-2-phenylsulfanyl-ethyl)-3-methoxy-4-oxo-azetidin-1-yl]-acetic acid 2-trimethylsilanyl-ethyl ester 
• 86255-90-5 [(2R,3S)-2-(1,1-Dimethyl-2,2-bis-phenylsulfanyl-ethyl)-3-methoxy-4-oxo-azetidin-1-yl]-acetic acid 2-trimethylsilanyl-ethyl ester 
• 86767-56-8 2-(1,1-Dimethyl-2,2-bis-phenylsulfanyl-ethyl)-[1,3]dioxolane 
• 80689-69-6 2-(2-Chloro-1,1-dimethyl-2-phenylsulfanyl-ethyl)-[1,3]dioxolane 
• 150849-75-5 Carbonic acid tert-butyl ester (1S,2S)-1-(1,1-dimethyl-2-phenylsulfanyl-ethyl)-2-methoxymethoxy-but-3-enyl ester 

Relevant academic research and scientific papers

A Joint Experimental-Computational Comparative Study of the Pd0-Catalysed Reactions of Aryl Iodides and Aldehydes with N, O, and S Tethers

The influence of the heteroatom (nitrogen, oxygen, and sulfur) on the course of the palladium-catalysed intramolecular reactions of aryl iodides and aldehydes having heteroatom-containing tethers has been explored by an extensive experimental-computationa

An approach to the C(17)-C(24) fragment of bryostatins: Applications of stereoselective trisubstituted alkene formation by palladium(0) catalysed coupling of enol acetates and vinylic bromides

The enol acetate 26 couples stereospecifically with the vinylic bromides 25 and 29 in the presence of tributyltin methoxide and a catalytic amount of dichlorobis(tri-o-tolylphosphine)palladium to give the βγ-unsaturated ketones 27 and 30 with retention of

Synthetic studies on bryostatins, potent antineoplastic agents: Synthesis of the C17-C27 fragment of C20 oxygenated bryostatins

Synthetic process towards the bottom half portion of C20 oxygenated series of bryostatins is described. The stereogenic center at C20 position was constructed through a hydroxyl group-directed epoxidation by using mCPBA. It was found that silver (I) salt is an effective and mild reagent for regioselective ring cleavage of α-bromoepoxides into the corresponding α-hydroxyketones via oxonium ion intermediates.