15093-47-7Relevant academic research and scientific papers
Thiourea derivatives, simple in structure but efficient enzyme inhibitors and mercury sensors
Alamery, Salman,Batiha, Gaber El-Saber,Bibi, Maryam,Khan, Ezzat,Muhammad, Mian,Rahman, Faizan Ur,Shah, Abdul Bari,Shahzad, Adnan,Tahir, Muhammad Nawaz,Ullah, Farhat,Zahoor, Muhammad
supporting information, (2021/08/06)
In this study six unsymmetrical thiourea derivatives, 1-isobutyl-3-cyclohexylthiourea (1), 1-tert-butyl-3-cyclohexylthiourea (2), 1-(3-chlorophenyl)-3-cyclohexylthiourea (3), 1-(1,1-dibutyl)-3-phenylthiourea (4), 1-(2-chlorophenyl)-3-phenylthiourea (5) an
METHODS OF PRODUCING METAL SUFLIDES, METAL SELENIDES, AND METAL SULFIDES/SELENIDES HAVING CONTROLLED ARCHITECTURES USING KINETIC CONTROL
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Paragraph 0204; 0205; 0221, (2017/05/28)
The present invention is directed to methods of preparing metal sulfide, metal selenide, or metal sulfide/selenide nanoparticles and the products derived therefrom. In various embodiments, the nanoparticles are derived from the reaction between precursor metal salts and certain sulfur- and/or selenium-containing precursors each independently having a structure of Formula (I), (II), or (III), or an isomer, salt, or tautomer thereof, where Q1,Q2,Q3,R1,R2,R3,R5, and X are defined within the specification.
Cerium ammonium nitrate-catalyzed aerobic oxidative coupling of dithiocarbamates: Facile synthesis of thioureas and bis(aminothiocarbonyl)disulfides
Li, Tian-Tian,Song, Xiang-Hai,Wang, Mei-Shuang,Ma, Ning
, p. 40054 - 40060 (2014/12/10)
Diverse disubstituted and trisubstituted thioureas were synthesized by the condensation of dithiocarbamate TEA (or DABCO) salts and amines using cerium ammonium nitrate (CAN) as a catalyst in high yields at room temperature. It is a one-pot method and it is unnecessary to isolate isothiocyanates. This reaction probably took place through nucleophilic addition of amines to isothiocyanates, which were generated by oxidative coupling of dithiocarbamates and the following decomposition of bis(aminothiocarbonyl)disulfides. When secondary amines and CS2served as the reactants, bis(aminothiocarbonyl)disulfides were obtained via tandem nucleophilic addition/oxidative coupling reactions in moderate to excellent yields. In all the coupling reactions, the oxidant was air and CAN possibly acted as an SET catalyst.
Arylthioureas with bromine or its equivalents gives no 'Hugerschoff' reaction product
Yella, Ramesh,Murru, Siva,Ali, Abdur Rezzak,Patel, Bhisma K.
experimental part, p. 3389 - 3393 (2010/08/22)
The in situ generated aryl-alkyl unsymmetrical thiourea obtained by the reaction of an aryl isothiocyanate with an aliphatic secondary amine on treatment with bromine or its equivalent gave exclusively a product having a thioamido guanidino moiety and not the expected Hugerschoff product 2-aminobenzothiazole. A plausible reaction mechanism has been proposed for this unprecedented transformation and the scope has been extended to various substrates. The Royal Society of Chemistry 2010.
