150930-60-2

Upstream product

• 145632-33-3 (S)-7a′-methyl-2′,3′,7′,7a′-tetrahydrospiro[[1,3]dithiolane-2,5′-inden]-1′(6′H)-one 
• 105088-15-1 (4aR,5S)-4,4a,5,6,7,8-hexahydro-4a,5-dimethyl-2(3H)-naphthalenone 
• 150930-59-9 3-((1R,6S)-2-Formyl-1,6-dimethyl-cyclohex-2-enyl)-propionic acid methyl ester 
• 156210-30-9 C₁₅H₂₄O₃S₃ 
• 150930-70-4 C₁₄H₂₂S₂ 
• 150930-58-8 (1S,8aR)-1,2,3,7,8,8a-hexahydro-6-methoxy-1,8a-dimethylnaphthalene 
• 150930-69-1 ((1′S,7a′R)-7a′-methyl-1′,2′,3′,6′,7′,7a′-hexahydrospiro[[1,3]dithiolane-2,5′-inden]-1′-yl)methanol 

Downstream Products

• 150930-62-4 (1R,6S)-2-(hydroxymethyl)-1,6-dimethyl-2-cyclohexene-1-butyronitrile 
• 150930-63-5 (1R,6S)-1,6-dimethyl-2-(vinyloxy)-2-cyclohexene-1-butyronitrile 
• 150930-61-3 3-[(1R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-1,6-dimethyl-cyclohex-2-enyl]-propan-1-ol 
• 150930-65-7 (1R,3R,6S)-3-<(E)-5-formyl-3-methyl-2-pentenyl>-1,6-dimethyl-2-methylenecyclohexanebutyronitrile 
• 150930-72-6 (1R,6S)-2-<(tert-butyldimethylsiloxy)methyl>-1,6-dimethyl-2-cyclohexene-1-butyronitrile 
• 150930-76-0 (1R,3R,6S)-3-<(E)-5-(1,3-dioxolan-2-yl)-3-methyl-2-pentenyl>-1,6-dimethyl-2-methylenecyclohexanebutyronitrile 
• 156210-32-1 Methanesulfonic acid 3-[(1R,6S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1,6-dimethyl-cyclohex-2-enyl]-propyl ester 
• 150930-64-6 4-[(1R,3R,6S)-1,6-Dimethyl-2-methylene-3-(2-oxo-ethyl)-cyclohexyl]-butyronitrile 
• 150930-71-5 methyl (1R,6S)-2-<(tert-butyldimethylsiloxy)methyl>-1,6-dimethyl-2-cyclohexene-1-propionate 

Relevant academic research and scientific papers

Total synthesis of the cembranoid diterpene lactone (+)-cleomeolide. Some remarkable conformational features of nine-membered belts linked in 2,6-fashion to a methylenecyclohexane core

The total synthesis of (+)-cleomeolide (1) has been accomplished. The key construction elements of this cembranoid lactone were (i) improved conversion of optically pure Wieland-Miescher ketone into dienol ether 12 and oxidative cleavage of the latter to

Enantioselective synthesis of (+)-cleomeolide, the structurally unique diterpene lactone constituent of Cleome viscosa

The first total synthesis of (+)-cleomeolide has been accomplished in enantioselective fashion from optically pure Wieland-Miescher ketone.