150955-48-9Relevant academic research and scientific papers
Different Co-ordination Modes of the Ligand (1-) in Complexes of Pd(II) and Pt(II). Crystal Stuctures of 2> and ClO4*CH2Cl2
Fornies, Juan,Martinez, Francisco,Navarro, Rafael,Urriolabeitia, Esteban P.,Welch, Alan W.
, p. 2147 - 2152 (1993)
The neutral complexes 2> (M = Pd or Pt; PR3 = PPh3 or PPh2Et) containing the P,S-bridging (1-) have been synthesised by reaction of the corresponding acetylacetonate (acac) derivatives with HP(S)Ph2.However, the reaction of the cationic complexes ClO4 (M = Pd or Pt) with HP(S)Ph2 affords mononuclear ClO4 in which the (1-) ligand is co-ordinated as a P,S-chelate.The anionic complex 22>has also been synthesised.The crystal structures of 2> and ClO4*CH2Cl2 have been determined by X-ray diffraction methods; the former adopts a boat conformation.
