Different Co-ordination Modes of the Ligand (1-) in Complexes of Pd(II) and Pt(II). Crystal Stuctures of 2> and ClO4*CH2Cl2

DOI: 10.1039/DT9930002147

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2147 - 2152 (1993)

Update date:2022-08-04

Topics:

Authors:

Fornies, Juan

Martinez, Francisco

Navarro, Rafael

Urriolabeitia, Esteban P.

Welch, Alan W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9930002147

The neutral complexes <2> (M = Pd or Pt; PR3 = PPh3 or PPh2Et) containing the P,S-bridging (1-) have been synthesised by reaction of the corresponding acetylacetonate (acac) derivatives with HP(S)Ph2.However, the reaction of the cationic complexes ClO4 (M = Pd or Pt) with HP(S)Ph2 affords mononuclear ClO4 in which the (1-) ligand is co-ordinated as a P,S-chelate.The anionic complex 2<2>has also been synthesised.The crystal structures of <2> and ClO4*CH2Cl2 have been determined by X-ray diffraction methods; the former adopts a boat conformation.

Full text of DOI:10.1039/DT9930002147

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Pd(SP(C₆H₅)2)(P(C₆H₅)3)2}⁽¹⁺⁾*ClO₄^(1-)={Pd(SP(C₆H₅)2)(P(C₆H₅)3)2}ClO₄

Cas No:150955-48-9

R&D Labs maybe for 150955-48-9

Shanghai Dynamic Industrial Co.,Ltd.

website:http://www.shdynamic.com

Contact:86-021 3392 6680

Address:Room 805 Information Tower, No.1403 Minsheng Road, Pudong New Area, Shanghai 200135, P. R. China
Jiangsu Mingchem Corporation

website:http://www.mingchem.com/en/index

Contact:0519-85170101-802

Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
Shanghai doly chemical Co.,Ltd

Contact:+86-21-34716221

Address:No.328,WuHe Roard,MinHang,ShangHai China
Nanjing yieldpharma co.ltd

Contact:13813902930 025-52714267

Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
NINGBO PANGS CHEM INT’L CO., LTD.

Contact:+86-0574-27666801

Address:Floor 21, Building 11, Xintiandi, No. 689, Shijiroad, Ningbo, Zhejiang, China

Relevant to this article

High Hole Mobility and Efficient Ambipolar Charge Transport in Heterocoronene-Based Ordered Columnar Discotics

Doi:10.1021/jacs.9b09126
(2019)
Doi:10.1039/jr9490002683
(1949)
Proline-based N-oxides as readily available and modular chiral catalysts. Enantioselective reactions of allyltrichlorosilane with aldehydes

Doi:10.1021/ol050814q
(2005)
Structural study of (oxodimethylenemethane)palladium and -platinum complexes

Doi:10.1021/om00005a060
(1995)
Neutral and cationic group 4 metal compounds containing octamethyldibenzotetraazaannulene (Me₈taa^2-) ligands. Synthesis and reactivity of (Me₈taa)MX₂ and (Me₈taa)MX⁺ complexes (M = Zr, Hf;

Doi:10.1021/om970814x
(1998)
Synthesis of 5-methyl-5-deaza nonclassical antifolates as inhibitors of dihydrofolate reductases and as potential antipneumocystis, antitoxoplasma, and antitumor agents

Doi:10.1021/jm00074a026
(1993)

Article Doi