Welcome to LookChem.com Sign In|Join Free

Article Doi

Different Co-ordination Modes of the Ligand (1-) in Complexes of Pd(II) and Pt(II). Crystal Stuctures of 2> and ClO4*CH2Cl2

DOI: 10.1039/DT9930002147

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2147 - 2152 (1993)

Update date:2022-08-04

Topics:

Authors:

Fornies, JuanFornies, Juan

Martinez, FranciscoMartinez, Francisco

Navarro, RafaelNavarro, Rafael

Urriolabeitia, Esteban P.Urriolabeitia, Esteban P.

Welch, Alan W.Welch, Alan W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9930002147

The neutral complexes <2> (M = Pd or Pt; PR3 = PPh3 or PPh2Et) containing the P,S-bridging (1-) have been synthesised by reaction of the corresponding acetylacetonate (acac) derivatives with HP(S)Ph2.However, the reaction of the cationic complexes ClO4 (M = Pd or Pt) with HP(S)Ph2 affords mononuclear ClO4 in which the (1-) ligand is co-ordinated as a P,S-chelate.The anionic complex 2<2>has also been synthesised.The crystal structures of <2> and ClO4*CH2Cl2 have been determined by X-ray diffraction methods; the former adopts a boat conformation.

View More

Products guided by the article

Product name:{Pd(SP(C6H5)2)(P(C6H5)3)2}(1+)*ClO4(1-)={Pd(SP(C6H5)2)(P(C6H5)3)2}ClO4

Cas No:150955-48-9

150955-48-9

R&D Labs maybe for 150955-48-9

Relevant to this article

Hot Product