Different Co-ordination Modes of the Ligand (1-) in Complexes of Pd(II) and Pt(II). Crystal Stuctures of 2> and ClO4*CH2Cl2

DOI: 10.1039/DT9930002147

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2147 - 2152 (1993)

Update date:2022-08-04

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Authors:

Fornies, Juan

Martinez, Francisco

Navarro, Rafael

Urriolabeitia, Esteban P.

Welch, Alan W.

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Article abstract of DOI:10.1039/DT9930002147

The neutral complexes <2> (M = Pd or Pt; PR3 = PPh3 or PPh2Et) containing the P,S-bridging (1-) have been synthesised by reaction of the corresponding acetylacetonate (acac) derivatives with HP(S)Ph2.However, the reaction of the cationic complexes ClO4 (M = Pd or Pt) with HP(S)Ph2 affords mononuclear ClO4 in which the (1-) ligand is co-ordinated as a P,S-chelate.The anionic complex 2<2>has also been synthesised.The crystal structures of <2> and ClO4*CH2Cl2 have been determined by X-ray diffraction methods; the former adopts a boat conformation.

Full text of DOI:10.1039/DT9930002147

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