151052-99-2Relevant academic research and scientific papers
Extracyclic Stereocontrolled Alkylation of (1R,5S)-4-Ethyl-6,6-dimethyl-3-(phenylsulfonyl)bicyclohept-3-en-2-one. A Highly Stereocontrolled Synthesis of (-)-Kanshone A
Kato, Michiharu,Watanabe, Masataka,Awen, Bahlul, Z.
, p. 5145 - 5152 (2007/10/02)
(1R,5S)-4-Ethyl-6,6-dimethyl-3-(phenylsulfonyl)bicyclohept-3-en-2-one (7) was prepared from (+)-nopinone (1) in six steps and 70percent overall yield via (1R,5R)-6,6-dimethyl-3-(phenylthio)bicyclohept-3-en-2-one (2).Alkylation reactions of 7
