151108-96-2Relevant academic research and scientific papers
Rearrangement of 3-(Trimethylsilylmethylthio)allyllithium
Miura, Katsukiyo,Oshima, Koichiro,Utimoto, Kiitiro
, p. 2584 - 2587 (2007/10/02)
Proton abstraction from 3-trimethylsilylmethylthio-1-propene by butyllithium followed by treatment with iodomethane provided 1-methylthio-4-trimethylsilyl-1-butene.Meanwhile, 1-trimethylsilylmethylthio-2-butene afforded 3-methyl-4-methylthio-1-trimethylsilyl-1-butene upon successive treatment with butyllithium and iodomethane.
