151231-67-3

Basic information

• Product Name: 2-Propen-1-amine, 3-phenyl-N-(triphenylphosphoranylidene)-, (2E)-
• CAS NO: 151231-67-3
• Molecular Formula: C27H24NP
• Molecular Weight: 393.468
• Mol File: 151231-67-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-amine, 3-phenyl-N-(triphenylphosphoranylidene)-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-amine, 3-phenyl-N-(triphenylphosphoranylidene)-, (2E)-(151231-67-3)
• EPA Substance Registry System: 2-Propen-1-amine, 3-phenyl-N-(triphenylphosphoranylidene)-, (2E)-(151231-67-3)

Safety Data

• Hazardous Substances Data: 151231-67-3(Hazardous Substances Data)

Upstream product

• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 4510-34-3 (Z)-cinnamyl alcohol 
• 21040-45-9 Cinnamyl acetate 
• 4392-24-9 Cinnamyl bromide 
• 103723-91-7 cinnamyl chloroformate 
• 57294-86-7 (E)-cinnamyl azide 
• 603-35-0 triphenylphosphine 
• 85669-63-2 (E)-cinnamyl diethyl phosphate 
• 85669-64-3 (Z)-diethyl (3-phenylallyl) phosphate 

Downstream Products

• 842172-35-4 [1-((3aR,5R,6R,6aS)-6-Iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-meth-(E)-ylidene]-((E)-3-phenyl-allyl)-amine 
• 842172-37-6 (3R,4R)-4-((3aR,5R,6R,6aS)-6-Iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-3-phenoxy-1-((E)-3-phenyl-allyl)-azetidin-2-one 
• 842172-36-5 (3S,4S)-4-((3aR,5R,6R,6aS)-6-Iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-3-phenoxy-1-((E)-3-phenyl-allyl)-azetidin-2-one 
• 728033-64-5 (3R,4R)-3-Benzyloxy-4-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-1-((E)-3-phenyl-allyl)-azetidin-2-one 
• 728033-61-2 (3S,4S)-3-Benzyloxy-4-((3aR,5R,6R,6aS)-6-iodo-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-1-((E)-3-phenyl-allyl)-azetidin-2-one 
• 151231-86-6 2-(4-Chloro-phenyl)-N-((E)-3-phenyl-allyl)-2-(triphenyl-λ⁵-phosphanylidene)-acetamide 
• 151231-87-7 2-(4-Fluoro-phenyl)-N-((E)-3-phenyl-allyl)-2-(triphenyl-λ⁵-phosphanylidene)-acetamide 
• 151231-85-5 2-Phenyl-N-((E)-3-phenyl-allyl)-2-(triphenyl-λ⁵-phosphanylidene)-acetamide 
• 158657-32-0 [1-(4-Methoxy-phenyl)-meth-(E)-ylidene]-((E)-3-phenyl-allyl)-amine 
• 120990-23-0 N-(phenylmethylidene)-N-[(E)-3-phenylprop-2-enyl]amine 
• 136844-01-4 2,2,3-Triphenyl-pent-4-enenitrile 
• 4335-60-8 (E)-cinnamylamine 

Relevant articles and documents

A simple one-pot method for the preparation of allyl azides from allyl alcohols using triphosgene: Synthesis of N1-cinnamyl azetidin-2-ones

A simple and efficient one-pot method for the preparation of allyl azides from allyl alcohols using triphosgene and sodium azide is described. An application of cinnamyl azide for the synthesis of various N1 -cinnamyl azetidin-2-ones is also described.

An efficient one-pot conversion of alkyl bromides into imines via the Staudinger reaction

A new one-pot procedure for transforming primary alkyl bromides into the corresponding imines via the Staudinger reaction has been developed. Acetonitrile was found to be an excellent solvent for azidation as well as the reaction of organic azide with triphenylphosphine and a carbonyl compound.

Iminophosphorane-mediated one-pot conversion of allyl azides into α-allylated nitriles by a consecutive staudinger reaction/aza-wittig reaction/3-aza-claisen rearrangement process

One-pot conversion of allyl azides 1 into nitriles 3 under mild and neutral conditions is reported. The method involves sequential treatment of 1 with triphenylphosphine and the corresponding ketene to give 3.