15130-13-9

Upstream product

• 100-47-0 benzonitrile 
• 13455-12-4 platinum(II) bromde 
• 10025-99-7 potassium tetrachloroplatinate(II) 
• 7558-02-3 potassium bromide 

Downstream Products

• 125784-54-5 {Pt(2)Br2} 
• 1083165-46-1 trans-[PtBr₂(benzonitrile)(N=C(Ph)ON(Me)CH(Ph))] 
• 1083165-49-4 trans-[PtBr₂(N=C(Ph)ON(Me)CH(Ph))2] 
• 1247793-91-4 trans-(benzonitrile)-dibromo[2,3-dihydro-3-ethoxycarbonyl-3-ethoxycarbonyl-methyl-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum 
• 1247793-90-3 trans-(benzonitrile)-dibromo[2,3-dihydro-3-(2-furyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum 
• 1247793-83-4 trans-(benzonitrile)-dibromo[2,3-dihydro-3-(2-methoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum 
• 1247793-86-7 trans-(benzonitrile)-dibromo[2,3-dihydro-3-(2,6-dimethoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum 
• 1247793-87-8 trans-(benzonitrile)-dibromo[2,3-dihydro-3-(2,4,6-trimethoxyphenyl)-2-methyl-5-phenyl-1,2,4-oxadiazole-κN(4)]platinum 
• 94792-87-7 (1,1'-bis(phenylthio)ferrocene)platinum dibromide 
• 77515-01-6 cis-PtBr₂(PF₂(OC₆H₅))2 
• 77490-13-2 cis-PtBr₂(PF(OC₆H₅)2)2 
• 96665-94-0 (1,1'-bis(benzylthio)ferrocene)platinum dibromide 

Relevant academic research and scientific papers

Trans-Di-μ-bromo-bis[bromo(triethylphosphine-κP)platinum(II)]

The title compound, [Pt2Br4(C6H 15P)2], is a centrosymmetric dinuclear platinum(II) complex consisting of two square-planar platinum centres connected by two bridging Br atoms

Synthesis and characterisation of mixed ligand Pt(ii) and Pt(iv) oxadiazoline complexes

The nitrile ligands in trans-[PtX2(PhCN)2] (X = Cl, Br, I) undergo sequential 1,3 dipolar cycloadditions with nitrones R 1R2C=N+(Me)-O- (R1 = H, R2 = Ph; R1 = CO2Et, R2 = CH 2CO2Et) to selectively form the Δ4-1,2,4- oxadiazoline complexes trans-[PtX2(PhCN) {N=C(Ph)-O-N(Me)-CR 1R2}] or trans-[PtX2{N=C(Ph)-O-N(Me)-CR 1R2}2] in high yields. The reactivity of the mixed ligand complexes trans-[PtX2(PhCN){N=C(Ph)-O-N(Me)-CR 1R2}] towards oxidation and ligand substitution was studied in more detail. Oxidation with Cl2 or Br2 provides the Pt(iv) species trans-[PtX2Y2(PhCN){N=C(Ph)-O-N(Me)- CH(Ph)}] (X, Y = Cl, Br). The mixed halide complex (X = Cl, Y = Br) undergoes halide scrambling in solution to form trans-[PtX(4-n)Y n(PhCN){N=C(Ph)-O-N(Me)-CH(Ph)}] as a statistical mixture. Ligand substitution in trans-[PtCl2(PhCN){N=C(Ph)-O-N(Me)-CR 1R2}] allows for selective replacement of the coordinated nitrile by nitrogen heterocycles such as pyridine, DMAP or 1-benzyl-2- methylimidazole to produce mixed ligand Pt(ii) complexes of the type trans- [PtX2(heterocycle){N=C(Ph)-O-N(Me)-CR1R2}]. All compounds were characterised by elemental analysis, mass spectrometry, IR and 1H, 13C and 195Pt NMR spectroscopy. Single-crystal X-ray structural analysis of (R,S)-trans-[PtBr 2{N=C(Ph)-O-N(Me)-CH(Ph)}2] and trans-[PtCl 2(C5H5N){N=C(Ph)-O-N(Me)-CH(Ph)}] confirms the molecular structure and the trans configuration of the heterocycles relative to each other. The Royal Society of Chemistry.