151370-46-6Relevant articles and documents
Stereoselective Synthesis of 1,2,4-Triols via Intramolecular Bis-silylation of Carbon-Carbon Triple Bonds Followed by Hydrogenation
Murakami, Masahiro,Oike, Hideaki,Sugawara, Mitsuru,Suginome, Michinori,Ito, Yoshihiko
, p. 3933 - 3946 (2007/10/02)
A new strategy for the stereoselective synthesis of 1,2,4-triols has been developed.An alkyne tethered to a disilanyl group, upon treatment with palladium acetate and tert-alkyl isocyanide, furnished an exocyclic bis-silylated olefin.Subsequent hydrogenat