941-15-1Relevant articles and documents
Synthesis and coordination ability of a partially silicon based crown ether
Reuter, Kirsten,Thiele, Günther,Hafner, Thomas,Uhlig, Frank,Von H?nisch, Carsten
, p. 13265 - 13268 (2016)
The first hybrid crown ether with two adjacent disilane fragments was synthesized through reaction of O(Si2Me4Cl)2 (3) with O(C2H4OH)2. By means of DFT calculations, the complexation ability of 1,2,4,5-tetrasila[12]crown-4 (7) towards Li+ was determined to be considerably higher compared to [12]crown-4.
London dispersion-driven hetero-aryl-aryl interactions in 1,2-diaryldisilanes
Linnemannst?ns, Marvin,Schwabedissen, Jan,Schultz, Aaron A.,Neumann, Beate,Stammler, Hans-Georg,Berger, Raphael J. F.,Mitzel, Norbert W.
supporting information, p. 2252 - 2255 (2020/03/04)
Non-covalent aryl-aryl interactions for the molecular structures of three 1,2-diaryltetramethyldisilanes X5C6-(SiMe2)2-C6Y5 (X ≠ Y; X, Y = H, F, Cl) were studied by single crystal X-ray and
Ruthenium-catalyzed alkoxylation of a hydrodisilane without Si[sbnd]Si bond cleavage
Kanno, Ken-ichiro,Aikawa, Yumi,Kyushin, Soichiro
supporting information, p. 9 - 12 (2016/12/23)
Transition metal-catalyzed synthesis of alkoxydisilanes via dehydrogenative coupling of a hydrodisilane with alcohols is reported. During the reaction, the Si[sbnd]Si bond is preserved effectively when [RuCl2(p-cymene)]2is used as a catalyst. Various alcohols can be used in this alkoxylation.