151390-51-1Relevant articles and documents
OXIDATION OF 1-METHYLCYCLOBUTANOL BY Pb(IV) AND Mn(III) COMPOUNDS
Kapustina, N.I.,Nikishin, G.I.
, p. 2189 - 2192 (1992)
The main product of the reaction of 1-methylcyclobutanol with Pb(OAc)4 in benzene is 1-phenyl-4-pentanone; the use of Mn(OAc)3 in acetic acid gives a mixture of 2,9-decanedione and methyl propyl ketone; 1-(chloro-, bromo-, thiocyano-, or ccyano)-4-pentanone is formed in the presence of the systems Pb(OAc)4-metal halide or Mn(OAc)3-metal halide. Keywords: oxidation, 1-methylcyclobutanol, lead tetraacetate, manganese triacetate, β-cleavage.