1514-10-9

Basic information

• Product Name: phenylbis(trifluoromethyl)phosphine
• Synonyms: phenylbis(trifluoromethyl)phosphine
• CAS NO: 1514-10-9
• Molecular Weight: 246.092
• Mol File: 1514-10-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: phenylbis(trifluoromethyl)phosphine(CAS DataBase Reference)
• NIST Chemistry Reference: phenylbis(trifluoromethyl)phosphine(1514-10-9)
• EPA Substance Registry System: phenylbis(trifluoromethyl)phosphine(1514-10-9)

Safety Data

• Hazardous Substances Data: 1514-10-9(Hazardous Substances Data)

Upstream product

• 2314-97-8 iodotrifluoromethane 
• 1104-52-5 tetraphenyl-cyclotetraphosphane 
• 644-97-3 Dichlorophenylphosphine 
• 956903-05-2 bis(4-cyanophenyl)phenylphosphonite 
• 81290-20-2 (trifluoromethyl)trimethylsilane 
• 887144-94-7 Togni's reagent II 
• 638-21-1 phenylphosphane 
• 13410-61-2 diphenyl phenylphosphonite 
• 2946-59-0 dicyano(phenyl)phosphine 
• 650-52-2 bis(trifluoromethyl)chlorophosphine 
• 591-51-5 phenyllithium 

Downstream Products

• 646-42-4 Phenyl-bistrifluormethyl-dibrom-phosphoran 

Relevant articles and documents

Cyanide initiated perfluoroorganylations with perfluoroorgano silicon compounds

Cyanophenylphosphanes, Ph2PCN or PhP(CN)2, do not react with Me3SiCF3 or Me3SiC6F5 in the absence of cyanide ions. Catalytic amounts of ionic cyanides such as [NEt4]CN

The synthesis of tris(perfluoroalkyl)phosphines

Tris(perfluoroalkyl)phosphines, of interest as turtable alternatives to the carbon monoxide ligand, can be synthesised by the nucleophile mediated reaction of perfluoroalkyltrimethylsilanes with triphenylphosphite; the method can be extended to diphosphines. The Royal Society of Chemistry 2005.