1514833-22-7Relevant academic research and scientific papers
Organocatalyzed Diastereo- and Enantioselective Conjugate Addition of Nitroalkanes to β-Silylmethylene Malonates: Direct Access to Enantioenriched Organosilanes
Chowdhury, Raghunath,Dubey, Akhil K.,Ghosh, Sunil K.
, p. 2962 - 2972 (2020)
Cinchona-alkaloid derived bifunctional thiourea catalyzed conjugate addition reaction of nitroalkanes to β-silylmethylene malonates is reported for direct access of densely functionalized enantioenriched organosilanes in good yields (up to 86 %) with exce
Cu(I)-NHC catalyzed Asymmetric Silyl transfer to unsaturated Lactams and Amides
Pace, Vittorio,Rae, James P.,Procter, David J.
supporting information, p. 476 - 479 (2014/04/03)
The first asymmetric silylation of unsaturated lactams and amides using Cu(I)-NHC catalysts and PhMe2SiBpin has been accomplished. The method has been exploited in an expedient asymmetric synthesis of the (R)-enantiomer of the nootropic drug oxiracetam.
