1516-96-7

Usage

Uses

Used in Chemical Synthesis:
4-Bromo-2,6-di-tert-butylanisole is used as a reagent in chemical synthesis for its ability to participate in cross-coupling reactions. This makes it a valuable tool in the creation of new compounds and materials.
Used in Scientific Research:
In the field of scientific research, 4-Bromo-2,6-di-tert-butylanisole is used as a research chemical to study its properties and potential applications. Its unique structure and reactivity make it an interesting subject for exploration in various chemical and material science studies.
Used in Laboratory Settings:
4-Bromo-2,6-di-tert-butylanisole is used in laboratory settings for its role in chemical reactions and synthesis. Its presence as a reagent in cross-coupling reactions allows researchers to create new compounds and materials, contributing to the advancement of chemical knowledge and technology.
Used in Material Science:
4-Bromo-2,6-di-tert-butylanisole is used as a component in the development of new materials, thanks to its reactivity and properties. Its involvement in cross-coupling reactions can lead to the creation of novel materials with unique characteristics, which can be applied in various industries and applications.

InChI:InChI=1/C15H23BrO/c1-14(2,3)11-8-10(16)9-12(13(11)17-7)15(4,5)6/h8-9H,1-7H3

Upstream product

• 1139-52-2 4-bromo-2,6-di-tert-butylphenol 
• 77-78-1 dimethyl sulfate 
• 1516-95-6 2,6-di-tert-butyl-anisole 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 507-20-0 tertiary butyl chloride 
• 75-65-0 tert-butyl alcohol 
• 115-11-7 isobutene 
• 74-88-4 methyl iodide 

Downstream Products

• 496067-55-1 1-(3,5-di-tert-butyl-4-methoxy-phenyl)-1H-imidazole 
• 782501-09-1 dichloro(3,5-di-tert-butyl-4-methoxyphenyl)phosphine 
• 255061-53-1 5-bis(3,5-di-t-butyl-4-methoxyphenyl)phosphinyl-1,3-benzodioxole 
• 1040917-22-3 2-(3,5-di-tert-butyl-4-methoxyphenyl)-3-trimethylsilanylethynyl-[1,10]phenanthroline 
• 233584-42-4 4-methoxy-3,5-di-tert-butylphenylboronic acid pinacol ester 
• 1032358-08-9 4-(3,5-di-tert-butyl-4-methoxyphenyl)pyridine 
• 4917-29-7 3,5-di(tertbutyl)-4-methoxybenzonitrile 
• 1107653-19-9 (S)-bis(3,5-di-t-butyl-4-methoxy-phenyl)(pyrrolidin-2-yl)methanol 
• 535925-40-7 bis(3,5-di-tert-butyl-4-methoxy-phenyl)phosphine oxide 
• 1516-95-6 2,6-di-tert-butyl-anisole 
• 223139-43-3 poly[3-(3,5-di-tert-butyl-4-methoxyphenyl)-thiophene] 
• 928306-64-3 3,3'-bis(3,5-di-tert-butyl-4-methoxyphenyl)-2,2'-bithiophene 

Relevant academic research and scientific papers

Tetra-Aza-Pentacenes by means of a One-Pot Friedl?nder Synthesis

Tetra-aza-pentacenes are attractive n-type small molecules for optoelectronic device applications, yet their syntheses are often laborious. Disclosed here is a one-pot Friedl?nder synthesis of 1,7,8,14-tetraazapentacece (tAP) derivatives (linear and/or be

An Isolable Silicon Analogue of a Ketone that Contains an Unperturbed Si=O Double Bond

Despite tremendous efforts to synthesize isolable compounds with an Si=O bond, silicon analogues of ketones that contain an unperturbed Si=O bond have remained elusive for more than 100 years. Herein, we report the synthesis of an isolable silicon analogu

Gold(I)-Catalyzed 7-exo-dig Cyclization: A Key Step to Access the Bicyclo[4.2.1]nonane Skeleton of Vibsatin A, a Neurotrophic Diterpenoid

Vibsatin A is a new neurotrophic vibsane-Type diterpenoid comprising a bridged bicyclo[4.2.1]nonane skeleton. Inspired by Sawamura's works, we generated the bicyclic backbone through a Conia-ene-derived 7-exo-dig cyclization from an enantiomerically enriched TIPS-based silyl enol ether. The reaction, catalyzed by a sensitive gold(I) complex, was efficiently performed on a large scale by glovebox free techniques. Furthermore, the shape of this system was exploited for subsequent installation of all of the stereogenic centers.

Highly Stereoselective Synthesis of 1,2-Disubstituted Indanes by Pd-Catalyzed Heck/Suzuki Sequence of Diarylmethyl Carbonates

A palladium-catalyzed Mizoroki-Heck-type cyclization/Suzuki-Miyaura cross-coupling cascade of diarylmethyl carbonates with arylboronic acid derivatives has been developed to deliver the corresponding 1,2-disubstituted indanes in good yields with high dias

Boraformylation and Silaformylation of Allenes

The boraformylation of allenes with B2(pin)2and a formate ester as boron and formyl source, respectively, proceeds in the presence of a copper catalyst. The reaction selectively affords the corresponding β-boryl β,γ-unsaturated aldeh

Preparation method of 2, 6-di-tert-butyl-4-bromoanisole

The invention provides a preparation method of 2, 6-di-tert-butyl-4-bromoanisole, which comprises the following steps of: adding a tert-butylation reagent into 4-bromoanisole under the catalysis of acid, and reacting to obtain 2, 6-di-tert-butyl-4-bromoanisole. According to the preparation method disclosed by the invention, 4-bromoanisole which is cheap and easy to obtain is taken as a raw material, a solvent is not required to be used, the 2, 6-di-tert-butyl-4-bromoanisole can be obtained only in one step, the preparation method has the advantages of high production efficiency and low production cost, and the raw materials and auxiliary reagents used in the reaction process are relatively low in toxicity and are more environment-friendly.

Phospholane-Phosphite Ligands for Rh Catalyzed Enantioselective Conjugate Addition: Unusually Reactive Catalysts for Challenging Couplings

The use of Rh catalysts derived from a phospholane-phosphite ligand were found to be more productive than the classic rhodium/BINAP system in enantioselective conjugate additions. These catalysts enable the use of lower amounts of aryl boronic acid in an

COMPOSITIONS AND METHODS FOR IMMUNE MODULATION AND TREATMENT OF CANCER

The disclosure relates to rexinoids, including compounds of the Formula (I) and (II) or a pharmaceutically acceptable salt, polymorph, prodrug, solvate or clathrate thereof. These rexinoids are useful for increasing PD-L1 in vivo, for treatment of cancer, and for inhibiting the onset of cancer.

Chiral 1,3-diaryl imidazolium salt carbene precursor, synthesis method thereof, metal salt compound and application

The invention discloses a chiral 1,3-diaryl imidazolium salt carbene precursor, a synthesis method thereof, a metal salt compound and application. The chiral 1,3-diaryl imidazolium salt carbene precursor forms a complex together with the copper to catalyz

Formation and Activation of Zr/Hf Bis(phenolate-ether) Precatalysts

Zr and Hf complexes of bis(phenolate-ether) (“O4”) ligands feature high activity, stereoselectivity and molecular weight capability for propene polymerization at high temperature. Here we report a simplified ligand synthesis and several new examples of O4