151620-08-5

Basic information

• Product Name: Methanesulfonic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)-benzyl ester
• Synonyms: Methanesulfonic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)-benzyl ester
• CAS NO: 151620-08-5
• Molecular Weight: 330.521
• Mol File: 151620-08-5.mol

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)-benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)-benzyl ester(151620-08-5)
• EPA Substance Registry System: Methanesulfonic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)-benzyl ester(151620-08-5)

Safety Data

• Hazardous Substances Data: 151620-08-5(Hazardous Substances Data)

Upstream product

• 81168-17-4 2-(tert-butyldimethylsiloxymethyl)benzyl alcohol 
• 124-63-0 methanesulfonyl chloride 

Downstream Products

• 195449-29-7 2,3;8,9;13,14-trisbenzo-1-phenyl-1-phospha-6,11-dithiacyclopentadecane-1-oxide 
• 195449-30-0 2,3;8,10;14,15-trisbenzo-1-phenyl-1-phospha-6,12-dithiacyclopentadecane-1-oxide 
• 195449-28-6 3-Phenyl-12,17-dithia-3-phospha-tricyclo[17.4.0.0^5,10]tricosa-1⁽²³⁾,5⁽¹⁰⁾,6,8,19,21-hexaene 3-oxide 
• 195449-27-5 3-Phenyl-12,16-dithia-3-phospha-tricyclo[16.4.0.0^5,10]docosa-1⁽²²⁾,5⁽¹⁰⁾,6,8,18,20-hexaene 3-oxide 
• 195449-26-4 3-Phenyl-12,15-dithia-3-phospha-tricyclo[15.4.0.0^5,10]henicosa-1⁽¹⁷⁾,5⁽¹⁰⁾,6,8,18,20-hexaene 3-oxide 
• 151620-09-6 C₂₂H₂₁Cl₂OP 
• 251961-48-5 2-(furfuryloxymethyl)benzyl alcohol 
• 251961-39-4 3-[2-(furfuryloxymethyl)benzyloxy]-1-diazo-2-propanone 
• 251961-49-6 2-(furfuryloxymethyl)benzyloxyacetic acid 
• 251961-50-9 2-(furfuryloxymethyl)benzyloxyacetic acid ethyl ester 
• 251961-35-0 2-(furfuryloxymethyl)benzyl diazoacetate 

Relevant articles and documents

Catalytic intramolecular addition of metal carbenes to remote furans

(formula presented) Diazo esters and diazo ketones linked to a furan undergo catalytic intramolecular addition of an intermediate metal carbene to the remote furan to form diendiones with ring sizes up to 17. Regioselectivity is catalyst dependent with addition to either the more or less substituted double bond. The high product yields and absence of need for high dilution suggest that this methodology is general for macrocycle preparations.