151670-73-4Relevant articles and documents
Circular Dichroic Method for the Determination of Absolute Configuration of α-Furfuryl Amines
Zhou, Wei-Shan,Zhu, Xue-You,Cheng, Jie-Fei
, p. 1501 - 1504 (1993)
An unambiguous assignment of absolute configuration of α-furfuryl amines by using the circular dichroic method is described.
Novel enantioselective synthesis of both enantiomers of furan-2-yl amines and amino acids
Demir, Ayhan S.,Sesenoglu, Oezge,Uelkue, Dincer,Arici, Cengiz
, p. 91 - 105 (2007/10/03)
A new enantioselective synthesis of furan-2-yl amines and amino acids is described, in which the key step is the oxazaborolidine-catalyzed enantioselective reduction of O-benzyl (E)- and (Z)-furan-2-yl ketone oximes to the corresponding chiral amines. The chirality of the furan-2-yl amines is fully controlled by the appropriate choice of the geometrical isomer of the O-benzyl oxime. Oxidation of the furan ring furnished amino acids in high yields.