151708-46-2Relevant academic research and scientific papers
Exploration of the mechanism of platinum(II)-catalyzed C-F activation: Characterization and reactivity of platinum(IV) fluoroaryl complexes relevant to catalysis
Wang, Tongen,Keyes, Lauren,Patrick, Brian O.,Love, Jennifer A.
, p. 1397 - 1407 (2012/04/10)
A series of Pt(IV) complexes relevant to catalytic C-F activation have been prepared and structurally characterized. PtIV-F complexes, formed by C-F activation, underwent transmetalation with Me2Zn to generate Me3PtIV
Activation volumes of substitution reactions on neutral and cationic organometallic platinum(IV) complexes: Definite proof of selective associative activation
Gallego, Carlos,Gonzalez, Gabriel,Martinez, Manuel,Merbach, Andre E.
, p. 2434 - 2438 (2008/10/09)
The activation volumes for the substitution reactions of a series of Pt(IV) sulfide organometallic complexes have been determined as a function of the entering and leaving ligands, as well as the inert organometallic skeleton. The results agree with the existence of a tunable associatively/dissociatively activated mechanism operating on these complexes, depending on the electronegativity of the substitution-inert spectator ligands.
