142827-73-4Relevant articles and documents
Controlling the position of anions relative to a pentafluorophenyl group
Giese, Michael,Albrecht, Markus,Wiemer, Katharina,Valkonen, Arto,Rissanen, Kari
, p. 1368 - 1372 (2012)
The position of an anion above an electron-deficient arene can be controlled by the geometry of appended directing groups. Here a series of ammonium substituted pentafluorophenyl derivatives is investigated. The presented results are one step on the way to find the ideal structural features for an effective and superior receptor for anion-π studies.
Exploration of the scope of Pt-catalyzed C-F activation
Keyes, Lauren,Sun, Alex D.,Love, Jennifer A.
supporting information; experimental part, p. 3985 - 3994 (2011/09/15)
We recently reported methods for the catalytic methylation and methoxylation of polyfluoroaryl imines utilizing [Pt2Me 4(SMe2)2] as a precatalyst. These methodologies provide a novel route to partially functiona
A practical route to fluoroalkyl- and fluoroarylamines by base-catalyzed [1,3]-proton shift reaction
Soloshonok,Soloshonok, Vadim A.,Kirilenko,Kirilenko, Alexander G.,Kukhar,Kukhar, Valery P.,Resnati,Resnati, Giuseppe
, p. 3119 - 3122 (2007/10/02)
The base-catalyzed [1,3]-proton shift reaction is shown to be an efficient general approach to fluoroalkyl and fluoroaryl amines starting from appropriate carbonyl compounds and benzylamine.
