151716-36-8

Basic information

• Product Name: METHYLDIHYDROJASMONATE
• Synonyms: (+)-(1S,2S)-Form
• CAS NO: 151716-36-8
• Molecular Formula: C₁₃H₂₂O₃
• Molecular Weight: 226.31200
• EINECS: 220-112-5
• Mol File: 151716-36-8.mol
• Article Data: 5

Chemical Properties

• Boiling Point: bp0.3 108°
• Flash Point: 130.8°C
• Appearance: /
• Density: 0.984g/cm³
• Vapor Pressure: 0.00071mmHg at 25°C
• Refractive Index: 1.453
• CAS DataBase Reference: METHYLDIHYDROJASMONATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYLDIHYDROJASMONATE(151716-36-8)
• EPA Substance Registry System: METHYLDIHYDROJASMONATE(151716-36-8)

Safety Data

• Hazardous Substances Data: 151716-36-8(Hazardous Substances Data)

Usage

Uses

Fragrance ingredient in perfumes, toilette and laundry products. Flavor ingredient producing fruit, tea, tobacco, and floral flavors.

InChI:InChI=1/C13H22O3/c1-3-4-5-6-11-10(7-8-12(11)14)9-13(15)16-2/h10-11H,3-9H2,1-2H3/t10-,11-/m1/s1

Upstream product

• 25564-22-1 2-pentyl-2-cyclopenten-1-one 
• 154828-89-4 2-pentyl-2,3-epoxy-1-cyclopentanone 
• 51806-24-7 methyl 1-hydroxy-2-pentylcyclopent-2-eneacetate 
• 24863-70-5 (3-oxo-2-pentyl-cyclopent-1-enyl)-acetic acid methyl ester 
• 878565-69-6 (Z)-methyl 2-(3-oxo-2-pentylidenecyclopentyl)acetate 
• 67-56-1 methanol 
• 51806-23-6 methyl 1-carboxymethyl-1-(2-pentyl-3-oxocyclopentyl)acetate 

Relevant articles and documents

Metal-ligand core-shell nanocomposite catalysts for the selective semihydrogenation of alkynes

Catalysts with a sheltered upbringing: Novel core-shell nanocomposite catalysts consisting of active metal nanoparticles encapsulated by macroligands have been prepared. They have Pd nanoparticles (PdNPs) as an active core and shell ligands having sulfoxide moieties coordinated to the PdNPs. The shell protects the catalyst from coordination by alkenes and allows the lead-free selective semihydrogenation of a wide range of alkynes without any additives (see scheme). Copyright

Rh-catalyzed highly enantioselective formation of functionalized cyclopentanes and cyclopentanones

A catalyst system, [Rh(COD)Cl]2-BINAP-AgSbF6, has been developed as a second-generation catalyst for the cycloisomerization of 1,6-enynes tethered by carbon chains. Cyclopentanes and cyclopentanones, which can contain functional grou

Enantioselective synthesis of both enantiomers of methyl dihydrojasmonate using solid-liquid asymmetric phase-transfer catalysis

Both enantiomers of methyl dihydrojasmonate (-)-1 and (+)-1 were obtained by a short route using asymmetric Michael addition of dimethyl malonate onto pentyl enone 3, followed by nonracemizing demethoxycarbonylation. The key enantioselective step involves a new system of asymmetric solid - liquid phase-transfer catalysis using solvent-free conditions. Enantiomeric excess as high as 90% (91% yield) was achieved.