15182-74-8

Basic information

• Product Name: N-Sulfinyl-o-toluidine
• Synonyms: N-Sulfinyl-o-toluidine;1-methyl-2-(sulfinylamino)benzene
• CAS NO: 15182-74-8
• Molecular Formula: C₇H₇NOS
• Molecular Weight: 153.2
• Mol File: 15182-74-8.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 233.7°C at 760 mmHg
• Flash Point: 95.1°C
• Appearance: /
• Density: 1.15g/cm³
• Vapor Pressure: 0.0841mmHg at 25°C
• Refractive Index: 1.576
• CAS DataBase Reference: N-Sulfinyl-o-toluidine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Sulfinyl-o-toluidine(15182-74-8)
• EPA Substance Registry System: N-Sulfinyl-o-toluidine(15182-74-8)

Safety Data

• Hazardous Substances Data: 15182-74-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H7NOS/c1-6-4-2-3-5-7(6)8-10-9/h2-5H,1H3

Upstream product

• 7719-09-7 thionyl chloride 
• 95-53-4 o-toluidine 
• 71-43-2 benzene 

Downstream Products

• 588-04-5 3,3'-dimethylazobenzene 
• 6676-90-0 phenyl-o-tolyl-diazene 
• 584-90-7 2,2'-dimethylazobenzene 
• 1520120-39-1 1-ethyl-2-(o-tolyl)-1-oxo-1λ⁶-thia-2,6-diazacyclohex-6-en-3-one 
• 1520120-10-8 3-{[ethyl(2-methylanilino)oxo-1λ⁶-sulfanylidene]amino}propanoic acid 
• 1520119-83-8 ethyl 3-{[ethyl(2-methylanilino)oxo-1λ⁶-sulfanylidene]amino}propanoate 
• 1520119-58-7 N-(o-tolyl)ethanesulfinamide 
• 122576-24-3 {ruthenium⁽⁰⁾ monocarbonyl(xylyl isonitrile)di(triphenylphosphine)(o-tolyliminooxosulphurane)} 
• 78584-41-5 (o-Aminobenzyl)-phenyl-ether 
• 22820-08-2 3,4-dihydro-1H-quinazoline-2-thione 
• 78584-39-1 o-N-Sulfinylamino-benzylbromid 
• 78584-37-9 o-N-Sulfinylamino-benzylchlorid 
• 501-60-0 1,2-di(p-tolyl)diazene 

Relevant articles and documents

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Substituted N-aryl alk-1-enesulfinamides: Preparation, properties and conversion into the corresponding indole compounds [1]

Reaction of vinylic organometallic derivatives with N-sulfinyl arenamines 2 affords the title sulfinamides 3. On heating their solutions in selected solvents to 80-124 °C, these sulfinamides are converted into the corresponding indoles 6, probably via a [3.3]-sigmatropic rearrangement to intermediates VIII which undergo an intramolecular carbophilic reaction of the nitrogen atom with the neighboring sulfine group, followed by elimination of HSOH. The triethyloxonium tetrafluoroborate- or boron trifluoride etherate catalyzed conversion 3 → 6 can be carried out at a much lower temperature. Elsevier,.