151858-75-2

Upstream product

• 151858-73-0 (4S,5R,2'R)-3-(2-azido-2-(2-methoxy-6-methylphenyl)acetyl)-4-methyl-5-phenyl-1,3-oxazolidin-2-one 
• 151858-72-9 (4S,5R)-3-(2-(2-methoxy-6-methylphenyl)acetyl)-4-methyl-5-phenyl-1,3-oxazolidin-2-one 
• 151858-71-8 (2-methoxy-6-methylphenyl)acetic acid 
• 151858-80-9 Acetic acid (R)-2-acetylamino-2-(2-methoxy-6-methyl-phenyl)-ethyl ester 
• 151858-74-1 (2R)-2-azido-2-(2-methoxy-6-methylphenyl)ethanol 

Downstream Products

• 151858-78-5 -4-<<2-hydroxy 1-(2-methoxy-6-methylphenyl)ethyl>amino>-4-oxo-2-butenoic acid 
• 139527-59-6 <3aR-<1<1S^*,3(R^*),5R^*,6R^*>,3aα,6α,7aβ>>-1-<<3-<2-(methoxymethoxy)-1-(2-methoxy-6-methylphenyl)ethyl>-8-methyl-2,4-dioxo-3,8-diazabicyclo<3.2.1>oct-6-yl>carbonyl>hexahydro-8,8-dimethyl-2,2-dioxo-3H-3a,6-methano-2,1-benzisothiazole 
• 139527-58-5 <3aR-<1<1S^*,3(R^*),5R^*,6R^*>,3aα,6α,7aβ>>-1-<<3-<2-hydroxy-1-(2-methoxy-6-methylphenyl)ethyl>-8-methyl-2,4-dioxo-3,8-diazabicyclo<3.2.1>oct-6-yl>carbonyl>hexahydro-8,8-dimethyl-2,2-dioxo-3H-3a,6-methano-2,1-benzisothiazole 
• 151858-79-6 (R)-1-<2-(acetyloxy)-1-(2-methoxy-6-methylphenyl)ethyl>-1H-pyrrole-2,5-dione 
• 151858-82-1 (R)-1-<2-hydroxy-1-(2-methoxy-6-methylphenyl)ethyl>-1H-pyrrole-2,5-dione 
• 151858-76-3 (R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-(2-methoxy-6-methyl-phenyl)-ethylamine 

Relevant academic research and scientific papers

The asymmetric synthesis of (-)-quinocarcin via a 1,3-dipolar cycloadditive strategy

Details of the asymmetric synthesis and complete structure elucidation of (-)-quinocarcin (1), an antitumor antibiotic that inhibits DNA (and in some systems RNA) synthesis, are reported. Key steps in the synthesis include the use of an auxiliary-controll