151908-68-8Relevant academic research and scientific papers
Ring opening of sugar-derived epoxides by TBAF/KHF2: An attractive alternative for the introduction of fluorine into the carbohydrate scaffold
Yan, Nan,Lei, Zhi-Wei,Su, Jia-Kun,Liao, Wei-Lin,Hu, Xiang-Guo
, p. 467 - 470 (2017/01/28)
A stable and commercially available reagent mixture, composed of tetrabutylammonium bifluoride/potassium bifluoride (TBAF/KHF2), was found to be effective for the nucleophilic ring opening reactions of sugar-derived epoxides with fluoride. Diff
Regioselectivity of Reductive Cleavage of Methyl 4,6-O-Benzylidene-3-deoxyhexopyranosides Containing Fluorine at the 2- or 3-Position with LiAlH4-AlCl3
Mori, Yoko,Morishima, Naohiko
, p. 2061 - 2067 (2007/10/02)
Reductive ring-opening reactions of the 4,6-O-benzylidene derivatives of methyl 3-deoxy-β-D-arabino-, 3-deoxy-α-D-ribo-, and 2-O-benzyl-3-deoxy-α-D-ribo-hexopyranosides with LiAlH4 and AlCl3 in the molar ratio of 4:4 gave the 4- and 6-O-benzyl derivatives
