151802-92-5Relevant academic research and scientific papers
Rearrangements in the course of fluorination by diethylaminosulfur trifluoride at C-2 of glycopyranosides: Some new parameters
Dax, Karl,Albert, Martin,Hammond, David,Illaszewicz, Carina,Purkarthofer, Thomas,Tscherner, Martin,Weber, Hansjoerg
, p. 427 - 448 (2002)
Reaction of a series of 21 glycosides unprotected at O-2 and featuring various configurations with DAST (diethylaminosulfur trifluoride) was monitored by 19F NMR spectroscopy. By means of the diacritical set of data (shift values and coupling c
Regioselectivity of Reductive Cleavage of Methyl 4,6-O-Benzylidene-3-deoxyhexopyranosides Containing Fluorine at the 2- or 3-Position with LiAlH4-AlCl3
Mori, Yoko,Morishima, Naohiko
, p. 2061 - 2067 (2007/10/02)
Reductive ring-opening reactions of the 4,6-O-benzylidene derivatives of methyl 3-deoxy-β-D-arabino-, 3-deoxy-α-D-ribo-, and 2-O-benzyl-3-deoxy-α-D-ribo-hexopyranosides with LiAlH4 and AlCl3 in the molar ratio of 4:4 gave the 4- and 6-O-benzyl derivatives
