151961-69-2Relevant academic research and scientific papers
POLYMER-SUPPORTED SOLUTION SYNTHESIS OF A HEPTAGLUCOSIDE HAVING PHYTOALEXIN ELICITOR ACTIVITY
Verduyn, R.,Klein, P. A. M. van der,Douwes, M.,Marel, G. A. van der,Boom, J. H. van
, p. 464 - 466 (2007/10/02)
An efficient synthesis of methyl heptaglucoside 2 using poly(ethyleneglycol)monomethyl ether as a polymer support is described.Elongation of the acceptor 11, anchored via a succinoyl linkage to PEG, with the appropriate glycosyl donors 4-6 and intermittent protective group manipulations gave fully protected heptamer 18.Deprotection of 18 furnished, after purification as its peracetate, title compound 2 in a good overall yield.
