1519887-70-7Relevant articles and documents
Synthesis of chiral building blocks for oxygenated terpenoids through a simultaneous and stereocontrolled construction of contiguous quaternary stereocenters by an ireland-claisen rearrangement
Akahori, Yoshihiro,Yamakoshi, Hiroyuki,Sawayama, Yuki,Hashimoto, Shunichi,Nakamura, Seiichi
, p. 720 - 735 (2014/04/03)
Methods for highly stereocontrolled syntheses of chiral building blocks with a triad of contiguous stereocenters, including two quaternary ones, have been developed. Ireland-Claisen rearrangement of the (Z)-silyl ketene acetal generated stereoselectively