15216-34-9Relevant academic research and scientific papers
A divergent approach for the total syntheses of cernuane-type and quinolizidine-type Lycopodium alkaloids
Nishikawa, Yasuhiro,Kitajima, Mariko,Kogure, Noriyuki,Takayama, Hiromitsu
experimental part, p. 1608 - 1617 (2009/05/09)
The divergent total syntheses of cernuane-type and quinolizidine-type Lycopodium alkaloids are described. A common intermediate 5 for the two types of alkaloids was assembled practically from (+)-citronellal via organocatalytic α-amination, followed by th
First asymmetric total syntheses of cernuane-type Lycopodium alkaloids cernuine, and cermizine D
Nishikawa, Yasuhiro,Kitajima, Mariko,Takayama, Hiromitsu
supporting information; experimental part, p. 1987 - 1990 (2009/04/18)
The first total syntheses of two cernuane-type Lycopodium alkaloids, (-)-cernuine and (+)-cermizine D, were accomplished starting from (+)-citronellal. The syntheses involved organocatalytic α-amination to afford oxazolidinone, which is used for diastereo
