152185-57-4

Upstream product

• 595566-32-8 (1S,2R,5R,6R,9R)-11-Benzyl-3,7,10-trioxa-11-aza-tricyclo[7.2.1.0^2,6]dodecane-4,5-diol 
• 595566-33-9 (1R,4S,5R,6S)-7-Benzyl-5-hydroxy-3,8-dioxa-7-aza-bicyclo[4.2.1]nonane-4-carbaldehyde 
• 152088-16-9 (2aS,2bR,4R,5R,5aS,7aR)-2-benzyl-2b,4,5,5a-tetrahydro-2-aza-1,6-dioxa-4,5-isopropylidenedioxyfuro[2',3':4,5]bicyclo[4.2.1]nonane 
• 152185-56-3 3-O-Allyl-1,2-O-isopropylidene-α-D-xylo-pentodialdose 
• 91882-92-7 3-O-allyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 20316-77-2 (3aR,5R,6S,6aR)-6-(allyloxy)-5-((R)-2,2-dimethyl[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxole 
• 108-24-7 acetic anhydride 
• 595566-34-0 (1R,4R,5R,6S)-7-Benzyl-4-hydroxymethyl-3,8-dioxa-7-aza-bicyclo[4.2.1]nonan-5-ol 

Relevant academic research and scientific papers

An Expeditious Enantiodivergent Synthesis of Chiral Oxepanes from D-Glucose by the Application of Intramolecular 1,3-Dipolar Nitrone Cycloaddition

The enantiomers of an oxepanoisoxazolidine and a chiral oxepane, potentially useful as precursors for naturally occuring oxepanes, were synthesised from D-glucose involving intramolecular 1,3-dipolar nitrone cycloaddition.

Synthesis of chiral oxepanes and pyrans by 3-O-allylcarbohydrate nitrone cycloaddition (3-OACNC)

3-O-Allylcarbohydrate nitrone cycloaddition (3-OACNC) furnished pyran and oxepane derivatives from 3-O-allyl hexose N-benzyl nitrones and 3-O-allyl furanoside-5-aldehyde N-benzyl/methyl nitrones. The regioselectivity of 3-OACNC was found to depend on the