An Expeditious Enantiodivergent Synthesis of Chiral Oxepanes from D-Glucose by the Application of Intramolecular 1,3-Dipolar Nitrone Cycloaddition

DOI: 10.1016/S0040-4039(00)73642-2

Source and publish data:

Tetrahedron Letters p. 3585 - 3588 (1993)

Update date:2022-07-30

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Authors:

Datta, Seema

Chattopadhyay, Partha

Mukhopadhyay, Ranjan

Bhattacharjya, Anup

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Article abstract of DOI:10.1016/S0040-4039(00)73642-2

The enantiomers of an oxepanoisoxazolidine and a chiral oxepane, potentially useful as precursors for naturally occuring oxepanes, were synthesised from D-glucose involving intramolecular 1,3-dipolar nitrone cycloaddition.

Full text of DOI:10.1016/S0040-4039(00)73642-2

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Product name:3,8-Dioxa-7-azabicyclo[4.2.1]nonane-4-methanol, 5-(acetyloxy)-7-(phenylmethyl)-, acetate (ester), (1R,4R,5R,6S)-

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