1522130-34-2

Upstream product

• 93-55-0 1-phenyl-propan-1-one 
• 2157-50-8 propiophenone oxime 
• 2251-50-5 pentafluorobenzoylchloride 
• 15989-99-8 2,3,4,5,6-pentafluorobenzoic anhydride 

Downstream Products

• 17799-61-0 3,4-dimethyl-2,5-diphenyl-1H-pyrrole 
• 103-26-4 Methyl cinnamate 

Relevant academic research and scientific papers

Arylketones as Aryl Donors in Palladium-Catalyzed Suzuki-Miyaura Couplings

Herein, we report the arylation, alkylation, and alkenylation of aryl ketones via a palladium-catalyzed Suzuki-Miyaura cross-coupling reaction. The use of the pyridine-oxazoline ligand is the key to the cleavage of the unstrained C-C bond. The late-stage arylation of aryl ketones derived from drugs and natural products demonstrated the synthetic utility of this protocol.

Copper-catalyzed homocoupling of ketoxime carboxylates for synthesis of symmetrical pyrroles

A novel and efficient copper-catalyzed homocoupling of ketoxime carboxylates has been developed for the synthesis of symmetrical pyrroles. This reaction tolerates a wide range of functional groups and provides a synthetically useful process to synthesize

Ruthenium-catalyzed cyclization of ketoxime acetates with DMF for synthesis of symmetrical pyridines

A novel ruthenium-catalyzed cyclization of ketoxime carboxylates with N,N-dimethylformamide (DMF) for the synthesis of tetrasubstituted symmetrical pyridines has been developed. A methyl carbon on DMF performed as a source of a one carbon synthon. And NaHSO3 plays a role in the reaction.