152252-33-0

Upstream product

• 100-39-0 benzyl bromide 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 81336-89-2 (2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-(2-(trimethylsilyl)ethoxy)tetrahydro-2H-pyran-3,4,5-triol 
• 81342-44-1 (2R,3R,4S,5R,6R)-2-(acetoxymethyl)-6-(2-(trimethylsilyl)ethoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 2916-68-9 2-(Trimethylsilyl)ethanol 
• 117253-04-0 2-(trimethylsilyl)ethyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 

Downstream Products

• 872120-60-0 (2R,4S,5R,6R)-4-Acetoxy-6-((1S,2R)-1,2,3-triacetoxy-propyl)-5-(2,2,2-trifluoro-acetylamino)-2-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 1010692-61-1 (2R,4aR,6S,7S,8R,8aR)-8-Benzyloxy-2-phenyl-6-[(2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 1010692-64-4 N-(2-{8-benzyloxy-2-phenyl-6-[3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy}-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-acetamide 
• 1010692-63-3 acetic acid 3-acetoxy-2-acetoxymethyl-5-acetylamino-6-{8-benzyloxy-2-phenyl-6-[3,4,5-tris-benzyloxy-6-(2-trimethylsilanyl-ethoxy)-tetrahydro-pyran-2-ylmethoxy]-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yloxy}-tetrahydro-pyran-4-yl ester 
• 1010692-62-2 C₇₂H₈₁NO₂₀Si 
• 152252-37-4 (2S,3S,4R,5S,6R)-3,4-Diacetoxy-5-acetylamino-6-((2R,3R,4S,5R)-3,4,5-tris-benzyloxy-6-fluoro-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 152252-35-2 2-(trimethylsilyl)ethyl 2,3,4-tri-O-benzyl-6-O-(methyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-β-D-mannopyranosyluronate)-β-D-glucopyranoside 

Relevant academic research and scientific papers

Odorless benzenethiols in synthesis of thioglycosides and its application for glycosylation reactions

p-Octyloxybenzenethiol (2) was synthesized as a new odorless benzenethiol. Moreover, preparation of thioglycosides using 2 and their application for glycosylation reactions were attempted. As a result, it was found that the thioglycosides were as excellen

Catalytic conversions of diazosugars

Catalytic diazo decomposition chemistry was explored with novel diazoacetate functionalized carbohydrates. In both glucose and galactose derivatives, aromatic cycloadditions with the benzyl protecting groups proved to be most favorable reactions. Replacing the benzyl groups by methoxy groups in the glucose system led to formation of 'carbene dimers'.

Facile preparation and utilization of a novel β-D-ManNAcA-donor: Methyl 2-benzoyloxyimino-1-bromo-2-deoxy-α-D-arabino-hexopyranuronate

The title β-D-ManNAcA-donor, the α-bromide of methyl 2-benzoyloxyimino-2-deoxy-D-arabino-hexopyranuronate 9, has been prepared from D-glucuronolactone in an overall yield of 21% for the seven steps required, all intermediates being securable in crystallin

Synthesis of a 2-Acetamido-2-deoxy-β-D-mannuronic Acid-Containing Artificial Glycolipid Corresponding to the Repeating Unit of a Teichuronic Acid from Micrococcus luteus

A new type of artificial glycolipid constituted with 2-acetamido-2-deoxy-β-D-mannuronic acid was synthesized utilizing a readily accessible building block, methyl 2-(benzoyloxy)iminoglycosuronate as the glycosyl donor.Stereocontrolled β-glycosidation of t