1523159-57-0Relevant academic research and scientific papers
Efficient synthesis of 1,3,5-benzotriazocines from tetrachloro-2-aza-1,3- dienes
Vasylyshyn, Roman Y.,Demydchuk, Bogdan A.,Rusanov, Eduard B.,Brovarets, Vladimir S.
supporting information, p. 714 - 719 (2014/01/17)
Easily accessible 1-aryl-2-aza-1,3-butadienes undergo a regioselective cyclocondensation with 2-(aminomethyl)aniline, giving rise to 1,3,5-benzotriazocines in good yields. The structure of the title compounds was proved with the aid of 1H and 13C NMR spectra and, in one case, single-crystal x-ray analysis. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications for the following free supplemental resource(s): Full experimental and spectral details.]
