15236-34-7

Upstream product

• 201230-82-2 carbon monoxide 
• 100-61-8 N-methylaniline 
• 71-36-3 butan-1-ol 
• 62-53-3 aniline 
• 3422-01-3 tert-butyl phenylcarbamate 
• 28131-24-0 tert-butyl N-methyl-N-(phenyl)carbamate 
• 50-00-0 formaldehyd 
• 7756-96-9 n-butyl anthranilate 

Relevant academic research and scientific papers

A novel pathway for the thermolysis of N-nitrosoanthranilates using flash vacuum pyrolysis leading to 7-aminophthalides

Flash vacuum pyrolysis of methyl N-methyl-N-nitrosoanthranilate leads to elimination of nitric oxide and disproportionation of the formed N-radical to 7-(methylamino)phthalide and methyl N-methylanthranilate. This transformation was found to be a convenient, solvent-free method for the preparation of 7-(methylamino)phthalides. An alternative route through pyrolysis of N-benzyl-N-methyl anthranilates was also investigated. This journal is

Palladium-catalyzed oxidative carbonylation of aromatic C-H bonds of N -alkylanilines with CO and alcohols for the synthesis of o -aminobenzoates

A Pd(II)-catalyzed C-H monocarbonylation of N-alkylanilines for the synthesis of o-aminobenzoates has been developed. Various aliphatic alcohols and phenol were tolerated in the reaction to afford the corresponding o-aminobenzoates in good yields under mild balloon pressure of CO.